KAlSi3O8

Potassium feldspar · K-feldspar, Orthoclase, Microcline, Sanidine

KAlSi3O8 is a stable, insulating aluminosilicate mineral that serves as a vital component in the Earth's crust and various industrial ceramic applications.

Crystal structure of KAlSi3O8 (triclinic, P-1 (No. 2))
Ground-state structure · Materials Project
Overview

About Potassium feldspar

KAlSi3O8 is a prominent member of the aluminosilicate family, characterized by a robust framework structure that grants it exceptional thermodynamic stability. As a wide-gap insulator, it serves as a foundational component in geological formations and industrial materials science.

This compound is widely recognized for its structural versatility, appearing in multiple distinct crystalline arrangements. Its durability and abundance make it a critical subject of study for understanding mineral stability and high-temperature processing in ceramic manufacturing.

At a glance

Key Properties

Cross-validated computational properties for Potassium feldspar, aggregated across 3 databases.

Band Gap

4.75–5.46 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

11
3 databases, 3 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for KAlSi3O8, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P-1 (No. 2)triclinic4.920.0000-7.9172.46
P-1 (No. 2)triclinic4.930.0042-7.9132.45
C2 (No. 5)monoclinic4.750.0069-7.9102.45
Cm (No. 8)monoclinic5.460.1890-7.7283.75
C2 (No. 5)Monoclinic2.45
P-1 (No. 2)Triclinic2.52
C2 (No. 5)Monoclinic2.59
C2 (No. 5)Monoclinic2.51
P-1 (No. 2)Triclinic2.61
P-1 (No. 2)Triclinic2.46
C2 (No. 5)
Uses

Applications

Where Potassium feldspar is used.

Ceramics manufacturingGlass productionGeochronologyPorcelain and enamel production
Reference

Frequently Asked Questions

Common questions about Potassium feldspar, answered from cross-validated data.

What is KAlSi3O8?

KAlSi3O8 is a stable, insulating aluminosilicate mineral that serves as a vital component in the Earth's crust and various industrial ceramic applications.

More questions
What is KAlSi3O8 used for?
Potassium feldspar (KAlSi3O8) is used in ceramics manufacturing, glass production, geochronology, and porcelain and enamel production.
What is the band gap of KAlSi3O8?
Potassium feldspar (KAlSi3O8) has a DFT-computed band gap of 4.75–5.46 eV across 11 reported structures.
Is KAlSi3O8 a metal, semiconductor, or insulator?
With a wide band gap up to 5.46 eV it is an insulator / wide-band-gap material.
Is KAlSi3O8 thermodynamically stable?
Yes — Potassium feldspar (KAlSi3O8) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
What is the crystal structure of KAlSi3O8?
The lowest-energy reported polymorph of Potassium feldspar (KAlSi3O8) is triclinic symmetry, space group P-1 (No. 2).
What is the density of KAlSi3O8?
The computed density of the ground-state structure of Potassium feldspar (KAlSi3O8) is 2.46 g/cm³.
How many polymorphs of KAlSi3O8 are known?
11 structures of KAlSi3O8 are reported across 3 databases, spanning 3 distinct space groups.
What elements does KAlSi3O8 contain?
Potassium feldspar (KAlSi3O8) contains Al, K, O, and Si (4 elements).
Where does the data for KAlSi3O8 come from?
KAlSi3O8 data is cross-referenced from materials_project, mpaloe, jarvis.
Comparison

How It Compares

Within the aluminosilicates and zeolite frameworks class.

Within the diverse class of aluminosilicates, KAlSi3O8 stands out as a primary alkali-bearing framework compared to the more structurally compact or distinctively layered members like Al2SiO5 or the calcium-rich Sr2Al2SiO7. While it shares the fundamental silicate-aluminate backbone found in NaAlSi3O8, its specific potassium coordination provides unique thermal and chemical properties that distinguish its behavior in both natural igneous processes and synthetic industrial applications.

Explore

Related Compounds

Other Aluminosilicates and Zeolite Frameworks in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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