ZrO2

Zirconium dioxide · Zirconia

Zirconium dioxide is a highly stable, insulating ceramic oxide widely used for its durability and dielectric properties in industrial and technological applications.

OZr
Crystal structure of ZrO2
Ground-state structure · Materials Project
Overview

About Zirconium dioxide

Zirconium dioxide is a robust, insulating ceramic material characterized by its exceptional thermodynamic stability. As a highly versatile oxide, it serves as a foundational building block for advanced materials science, prized for its ability to maintain structural integrity under demanding conditions. Its electronic properties make it an essential dielectric component in modern technological applications. The extensive body of structural data available for this compound underscores its significance as a primary material in both industrial and research settings. Its prevalence in diverse structural configurations highlights its adaptability and importance in engineering high-durability components.

At a glance

Key Properties

Cross-validated computational properties for Zirconium dioxide, aggregated across 4 databases.

Band Gap

2.86–4.19 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

510
4 databases, 50 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting ZrO2.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Zirconium dioxide is used.

Dental ceramicsOxygen sensorsThermal barrier coatingsHigh-k dielectric layers in semiconductorsSolid oxide fuel cells
Intellectual Property

Patent Landscape

53 patents reference ZrO2 or close compositional variants.

PatentTitleAssigneeGranted
4843046Ceramic composition of high dielectric constant comprising PbO.sub.3, La.sub.2 O.sub.3, MO, ZrO.sub.2 and TiO.
7012036ZrO2-Al2O3 composite ceramic material and production method thereof
12102979Coated composites of Al2O3—CeO2/ZrO2 and a method for their production
4560669Silicon nitride sintered bodies of Si.sub.3 N.sub.4, Y.sub.2 O.sub.3, MgO and ZrO.sub.2
11014853Y2O3—ZrO2 erosion resistant material for chamber components in plasma environments
8808523Method for forming ZrO2 film by plasma electrolytic oxidation
11530135Method of applying hierarchical porous ZrO2 material
4933154Production of ZrO.sub.2 powder of very fine particle size
9373677Doping of ZrO2 for DRAM applications
5486491Ceramic ferroelectric composite material - BSTO-ZrO.sub.2
Reference

Frequently Asked Questions

Common questions about Zirconium dioxide, answered from cross-validated data.

What is ZrO2?

Zirconium dioxide is a highly stable, insulating ceramic oxide widely used for its durability and dielectric properties in industrial and technological applications.

More questions
What is ZrO2 used for?
Zirconium dioxide (ZrO2) is used in dental ceramics, oxygen sensors, thermal barrier coatings, high-k dielectric layers in semiconductors, and solid oxide fuel cells.
What is the band gap of ZrO2?
Zirconium dioxide (ZrO2) has a DFT-computed band gap of 2.86–4.19 eV across 510 reported structures.
Is ZrO2 a metal, semiconductor, or insulator?
With a wide band gap up to 4.19 eV it is an insulator / wide-band-gap material.
Is ZrO2 thermodynamically stable?
Yes — Zirconium dioxide (ZrO2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of ZrO2 are known?
510 structures of ZrO2 are reported across 4 databases, spanning 50 distinct space groups.
How is ZrO2 synthesized?
Literature-reported routes for ZrO2 include sol gel, solid state (10 procedures documented).
What elements does ZrO2 contain?
Zirconium dioxide (ZrO2) contains O and Zr (2 elements).
Where does the data for ZrO2 come from?
ZrO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a primary oxide in its class, zirconium dioxide serves as a benchmark for high-performance ceramic materials, offering superior stability and insulating characteristics that define the performance standards for similar refractory oxides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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