WF6

Tungsten hexafluoride · Tungsten(VI) fluoride

Tungsten hexafluoride is a stable, insulating inorganic compound used extensively as a precursor for depositing tungsten metal in semiconductor fabrication.

FW
Crystal structure of WF6
Ground-state structure · Materials Project
Overview

About Tungsten hexafluoride

Tungsten hexafluoride is a highly significant inorganic compound characterized by its insulating electronic nature and exceptional thermodynamic stability. Its ability to remain stable on the convex hull makes it a reliable precursor in industrial chemical processes.

Due to its unique chemical properties, this compound is widely employed in the semiconductor industry. It serves as a critical source of tungsten for the deposition of thin films, which are essential for creating conductive pathways in modern microelectronic devices.

At a glance

Key Properties

Cross-validated computational properties for Tungsten hexafluoride, aggregated across 3 databases.

Band Gap

5.37 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

17
3 databases, 5 space groups
Uses

Applications

Where Tungsten hexafluoride is used.

Chemical vapor depositionSemiconductor manufacturingMicroelectronics fabrication
Intellectual Property

Patent Landscape

4 patents reference WF6 or close compositional variants.

PatentTitleAssigneeGranted
5963828Method for tungsten nucleation from WF.sub.6 using titanium as a reducing agent
4751101Low stress tungsten films by silicon reduction of WF.sub.6
9748105Tungsten deposition with tungsten hexafluoride (WF6) etchback
5997949Synthesis of W-Si-N films by chemical vapor deposition using WF.sub.6, SiH.sub.4 and NH.sub.3
Reference

Frequently Asked Questions

Common questions about Tungsten hexafluoride, answered from cross-validated data.

What is WF6?

Tungsten hexafluoride is a stable, insulating inorganic compound used extensively as a precursor for depositing tungsten metal in semiconductor fabrication.

More questions
What is WF6 used for?
Tungsten hexafluoride (WF6) is used in chemical vapor deposition, semiconductor manufacturing, and microelectronics fabrication.
What is the band gap of WF6?
Tungsten hexafluoride (WF6) has a DFT-computed band gap of 5.37 eV across 17 reported structures.
Is WF6 a metal, semiconductor, or insulator?
With a wide band gap up to 5.37 eV it is an insulator / wide-band-gap material.
Is WF6 thermodynamically stable?
Yes — Tungsten hexafluoride (WF6) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of WF6 are known?
17 structures of WF6 are reported across 3 databases, spanning 5 distinct space groups.
What elements does WF6 contain?
Tungsten hexafluoride (WF6) contains F and W (2 elements).
Where does the data for WF6 come from?
WF6 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone member of its chemical class in this context, tungsten hexafluoride is distinguished by its high degree of structural characterization across multiple databases, reflecting its status as a foundational material for advanced thin-film manufacturing.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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