SnF4

tin(IV) fluoride · stannic fluoride

Tin(IV) fluoride is a stable, insulating inorganic compound containing tin and fluorine that is primarily utilized in chemical synthesis.

FSn
Crystal structure of SnF4
Ground-state structure · Materials Project
Overview

About tin(IV) fluoride

Tin(IV) fluoride is a robust inorganic compound characterized by its insulating electronic nature. As a thermodynamically stable phase, it maintains structural integrity under standard conditions, making it a reliable subject for fundamental materials research.

With extensive structural data available across multiple databases, this compound serves as a key reference point for tin-based fluorides. Its chemical behavior is defined by the high electronegativity of fluorine coupled with the tetravalent state of tin, facilitating its use in specialized chemical processes.

At a glance

Key Properties

Cross-validated computational properties for tin(IV) fluoride, aggregated across 3 databases.

Band Gap

2.15–3.11 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

52
3 databases, 14 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting SnF4.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where tin(IV) fluoride is used.

fluorinating agentchemical synthesiscatalyst precursor
Reference

Frequently Asked Questions

Common questions about tin(IV) fluoride, answered from cross-validated data.

What is SnF4?

Tin(IV) fluoride is a stable, insulating inorganic compound containing tin and fluorine that is primarily utilized in chemical synthesis.

More questions
What is SnF4 used for?
tin(IV) fluoride (SnF4) is used in fluorinating agent, chemical synthesis, and catalyst precursor.
What is the band gap of SnF4?
tin(IV) fluoride (SnF4) has a DFT-computed band gap of 2.15–3.11 eV across 52 reported structures.
Is SnF4 a metal, semiconductor, or insulator?
With a wide band gap up to 3.11 eV it is an insulator / wide-band-gap material.
Is SnF4 thermodynamically stable?
Yes — tin(IV) fluoride (SnF4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SnF4 are known?
52 structures of SnF4 are reported across 3 databases, spanning 14 distinct space groups.
How is SnF4 synthesized?
Literature-reported routes for SnF4 include solid state (7 procedures documented).
What elements does SnF4 contain?
tin(IV) fluoride (SnF4) contains F and Sn (2 elements).
Where does the data for SnF4 come from?
SnF4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone representative of its specific tin-fluoride chemistry, this compound serves as a critical benchmark for understanding the stability and insulating characteristics of tetravalent metal halides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze SnF4 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →