SnF2
stannous fluoride · tin(II) fluoride
Stannous fluoride is a stable, insulating inorganic compound commonly used as a key active ingredient in dental hygiene products to promote oral health.

About stannous fluoride
Stannous fluoride is a chemically stable inorganic compound that exists as a wide-band-gap insulator. Its robust thermodynamic profile makes it a reliable material for applications requiring consistent chemical performance and stability under ambient conditions. The compound is characterized by a high degree of structural diversity, with numerous reported crystalline arrangements across materials databases. This structural flexibility underscores its significance in both fundamental solid-state research and practical industrial applications. Its role as a source of fluoride ions is central to its utility in modern chemical formulations.
Key Properties
Cross-validated computational properties for stannous fluoride, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where stannous fluoride is used.
Frequently Asked Questions
Common questions about stannous fluoride, answered from cross-validated data.
What is SnF2?
Stannous fluoride is a stable, insulating inorganic compound commonly used as a key active ingredient in dental hygiene products to promote oral health.
What is SnF2 used for?
What is the band gap of SnF2?
Is SnF2 a metal, semiconductor, or insulator?
Is SnF2 thermodynamically stable?
How many polymorphs of SnF2 are known?
What elements does SnF2 contain?
Where does the data for SnF2 come from?
How It Compares
As a thermodynamically stable fluoride, this compound serves as a benchmark for inorganic tin-based materials. Its status as a well-documented and highly studied substance distinguishes it within the broader landscape of metal halides, where it is valued for its specific reactivity and insulating electronic character.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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