SnF2

stannous fluoride · tin(II) fluoride

Stannous fluoride is a stable, insulating inorganic compound commonly used as a key active ingredient in dental hygiene products to promote oral health.

FSn
Crystal structure of SnF2
Ground-state structure · Materials Project
Overview

About stannous fluoride

Stannous fluoride is a chemically stable inorganic compound that exists as a wide-band-gap insulator. Its robust thermodynamic profile makes it a reliable material for applications requiring consistent chemical performance and stability under ambient conditions. The compound is characterized by a high degree of structural diversity, with numerous reported crystalline arrangements across materials databases. This structural flexibility underscores its significance in both fundamental solid-state research and practical industrial applications. Its role as a source of fluoride ions is central to its utility in modern chemical formulations.

At a glance

Key Properties

Cross-validated computational properties for stannous fluoride, aggregated across 3 databases.

Band Gap

3.27 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

170
3 databases, 27 space groups
Uses

Applications

Where stannous fluoride is used.

toothpastemouthwashdental treatmentsfluoridation agents
Reference

Frequently Asked Questions

Common questions about stannous fluoride, answered from cross-validated data.

What is SnF2?

Stannous fluoride is a stable, insulating inorganic compound commonly used as a key active ingredient in dental hygiene products to promote oral health.

More questions
What is SnF2 used for?
stannous fluoride (SnF2) is used in toothpaste, mouthwash, dental treatments, and fluoridation agents.
What is the band gap of SnF2?
stannous fluoride (SnF2) has a DFT-computed band gap of 3.27 eV across 170 reported structures.
Is SnF2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.27 eV it is an insulator / wide-band-gap material.
Is SnF2 thermodynamically stable?
Yes — stannous fluoride (SnF2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SnF2 are known?
170 structures of SnF2 are reported across 3 databases, spanning 27 distinct space groups.
What elements does SnF2 contain?
stannous fluoride (SnF2) contains F and Sn (2 elements).
Where does the data for SnF2 come from?
SnF2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a thermodynamically stable fluoride, this compound serves as a benchmark for inorganic tin-based materials. Its status as a well-documented and highly studied substance distinguishes it within the broader landscape of metal halides, where it is valued for its specific reactivity and insulating electronic character.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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