SbF5
Antimony pentafluoride · Antimony(V) fluoride
Antimony pentafluoride is a powerful, thermodynamically stable Lewis acid widely used as a key component in superacid chemistry.

About Antimony pentafluoride
Antimony pentafluoride is a highly reactive inorganic compound recognized for its exceptional Lewis acidity. As a thermodynamically stable species, it serves as a foundational component in the synthesis of powerful superacid systems, which are essential for facilitating difficult chemical transformations. Its insulating electronic character underscores its role as a specialized reagent rather than a conductive material. Due to its intense reactivity, it is handled with extreme care in industrial and laboratory settings. It remains a subject of significant interest in structural chemistry, with numerous documented configurations reflecting its complex coordination behavior.
Key Properties
Cross-validated computational properties for Antimony pentafluoride, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where Antimony pentafluoride is used.
Frequently Asked Questions
Common questions about Antimony pentafluoride, answered from cross-validated data.
What is SbF5?
Antimony pentafluoride is a powerful, thermodynamically stable Lewis acid widely used as a key component in superacid chemistry.
What is SbF5 used for?
What is the band gap of SbF5?
Is SbF5 a metal, semiconductor, or insulator?
Is SbF5 thermodynamically stable?
How many polymorphs of SbF5 are known?
What elements does SbF5 contain?
Where does the data for SbF5 come from?
How It Compares
As a standalone reagent in its class, antimony pentafluoride is distinguished by its extreme chemical potency and its ability to act as one of the strongest known Lewis acids, setting a high benchmark for reactivity compared to less aggressive fluorinated compounds.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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