SbF5

Antimony pentafluoride · Antimony(V) fluoride

Antimony pentafluoride is a powerful, thermodynamically stable Lewis acid widely used as a key component in superacid chemistry.

FSb
Crystal structure of SbF5
Ground-state structure · Materials Project
Overview

About Antimony pentafluoride

Antimony pentafluoride is a highly reactive inorganic compound recognized for its exceptional Lewis acidity. As a thermodynamically stable species, it serves as a foundational component in the synthesis of powerful superacid systems, which are essential for facilitating difficult chemical transformations. Its insulating electronic character underscores its role as a specialized reagent rather than a conductive material. Due to its intense reactivity, it is handled with extreme care in industrial and laboratory settings. It remains a subject of significant interest in structural chemistry, with numerous documented configurations reflecting its complex coordination behavior.

At a glance

Key Properties

Cross-validated computational properties for Antimony pentafluoride, aggregated across 3 databases.

Band Gap

0.48–3.68 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

33
3 databases, 9 space groups
Uses

Applications

Where Antimony pentafluoride is used.

Superacid preparationFluorinating agentCatalyst in organic synthesisPolymerization initiator
Reference

Frequently Asked Questions

Common questions about Antimony pentafluoride, answered from cross-validated data.

What is SbF5?

Antimony pentafluoride is a powerful, thermodynamically stable Lewis acid widely used as a key component in superacid chemistry.

More questions
What is SbF5 used for?
Antimony pentafluoride (SbF5) is used in superacid preparation, fluorinating agent, catalyst in organic synthesis, and polymerization initiator.
What is the band gap of SbF5?
Antimony pentafluoride (SbF5) has a DFT-computed band gap of 0.48–3.68 eV across 33 reported structures.
Is SbF5 a metal, semiconductor, or insulator?
With a wide band gap up to 3.68 eV it is an insulator / wide-band-gap material.
Is SbF5 thermodynamically stable?
Yes — Antimony pentafluoride (SbF5) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SbF5 are known?
33 structures of SbF5 are reported across 3 databases, spanning 9 distinct space groups.
What elements does SbF5 contain?
Antimony pentafluoride (SbF5) contains F and Sb (2 elements).
Where does the data for SbF5 come from?
SbF5 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone reagent in its class, antimony pentafluoride is distinguished by its extreme chemical potency and its ability to act as one of the strongest known Lewis acids, setting a high benchmark for reactivity compared to less aggressive fluorinated compounds.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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