Sb2O3

Antimony trioxide · Antimony(III) oxide, Senarmontite, Valentinite

Antimony trioxide is a stable, insulating oxide primarily used as a flame retardant and an industrial additive for glass and plastic manufacturing.

OSb
Crystal structure of Sb2O3
Ground-state structure · Materials Project
Overview

About Antimony trioxide

Antimony trioxide is a thermodynamically stable inorganic compound that exists in multiple structural forms. As a wide-gap insulator, it exhibits distinct electronic properties that make it highly versatile for industrial applications requiring chemical stability and specific optical characteristics.

This material is extensively utilized due to its effectiveness as a flame retardant synergist when combined with halogenated compounds. Beyond fire safety, it serves as a critical additive in the production of high-quality glass, ceramics, and specialized polymers to improve clarity and durability.

At a glance

Key Properties

Cross-validated computational properties for Antimony trioxide, aggregated across 4 databases.

Band Gap

1.31–3.34 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

62
4 databases, 14 space groups
Uses

Applications

Where Antimony trioxide is used.

Flame retardant synergistOpacifying agent in ceramicsClarifying agent in glass productionPolyethylene terephthalate catalystPigment production
Reference

Frequently Asked Questions

Common questions about Antimony trioxide, answered from cross-validated data.

What is Sb2O3?

Antimony trioxide is a stable, insulating oxide primarily used as a flame retardant and an industrial additive for glass and plastic manufacturing.

More questions
What is Sb2O3 used for?
Antimony trioxide (Sb2O3) is used in flame retardant synergist, opacifying agent in ceramics, clarifying agent in glass production, polyethylene terephthalate catalyst, and pigment production.
What is the band gap of Sb2O3?
Antimony trioxide (Sb2O3) has a DFT-computed band gap of 1.31–3.34 eV across 62 reported structures.
Is Sb2O3 a metal, semiconductor, or insulator?
With a wide band gap up to 3.34 eV it is an insulator / wide-band-gap material.
Is Sb2O3 thermodynamically stable?
Yes — Antimony trioxide (Sb2O3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Sb2O3 are known?
62 structures of Sb2O3 are reported across 4 databases, spanning 14 distinct space groups.
What elements does Sb2O3 contain?
Antimony trioxide (Sb2O3) contains O and Sb (2 elements).
Where does the data for Sb2O3 come from?
Sb2O3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a prominent and well-characterized oxide, this compound serves as a benchmark for antimony-based materials. Its high structural diversity, evidenced by numerous reported configurations, positions it as a foundational material in the study of group fifteen metal oxides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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