SO3

Sulfur trioxide · Sulfuric anhydride

Sulfur trioxide is a stable, insulating oxide of sulfur that functions as the primary industrial precursor for the manufacturing of sulfuric acid.

OS
Crystal structure of SO3
Ground-state structure · Materials Project
Overview

About Sulfur trioxide

Sulfur trioxide is a highly reactive inorganic compound that exists as a wide-gap insulating oxide. As a thermodynamically stable phase, it occupies a significant position in chemical synthesis, particularly due to its role as the primary precursor for large-scale industrial acid production. Its structural versatility is evidenced by the numerous reported configurations across major materials databases. This compound is essential for manufacturing processes that require strong dehydrating agents and chemical intermediates. Its ability to act as a potent Lewis acid makes it indispensable in the synthesis of various sulfonated organic compounds and industrial detergents.

At a glance

Key Properties

Cross-validated computational properties for Sulfur trioxide, aggregated across 4 databases.

Band Gap

5.18 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

63
4 databases, 18 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting SO3.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where Sulfur trioxide is used.

Sulfuric acid productionSulfonation of organic compoundsDetergent manufacturingChemical synthesis intermediate
Intellectual Property

Patent Landscape

21 patents reference SO3 or close compositional variants.

PatentTitleAssigneeGranted
3950493Process for absorbing SO.sub.3
4548789Mono-stage device to generate gaseous SO.sub.3 from melted sulphur
4419423Nonaqueous cells employing heat-treated MnO.sub.2 cathodes and a PC-DME-LiCF.sub.3 SO.sub.3 electrolyte
4766104Process for producing a V.sub.2 O.sub.5 -and-alkali-metal-sulfate-containing catalyst for oxidizing SO.sub.2 t
4304759Process for obtaining metal oxide and SO.sub.2 -containing gases essentially free of SO.sub.3 and H.sub.2 SO.s
9487401Process for the oxidation of SO2 to SO3
5387402Contact reactor for a quasi-isothermal catalytic oxidation of SO.sub.2 to SO.sub.3 and method of operating sam
4331632Catalytic cartridge SO.sub.3 decomposer
8980497Secondary battery including anode with a coating containing a SO3 containing compound
6500402Catalyst for oxidizing SO2 to SO3 and utilization of the catalyst in a method for producing sulfuric acid
Reference

Frequently Asked Questions

Common questions about Sulfur trioxide, answered from cross-validated data.

What is SO3?

Sulfur trioxide is a stable, insulating oxide of sulfur that functions as the primary industrial precursor for the manufacturing of sulfuric acid.

More questions
What is SO3 used for?
Sulfur trioxide (SO3) is used in sulfuric acid production, sulfonation of organic compounds, detergent manufacturing, and chemical synthesis intermediate.
What is the band gap of SO3?
Sulfur trioxide (SO3) has a DFT-computed band gap of 5.18 eV across 63 reported structures.
Is SO3 a metal, semiconductor, or insulator?
With a wide band gap up to 5.18 eV it is an insulator / wide-band-gap material.
Is SO3 thermodynamically stable?
Yes — Sulfur trioxide (SO3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of SO3 are known?
63 structures of SO3 are reported across 4 databases, spanning 18 distinct space groups.
How is SO3 synthesized?
Literature-reported routes for SO3 include sol gel, solid state (10 procedures documented).
What elements does SO3 contain?
Sulfur trioxide (SO3) contains O and S (2 elements).
Where does the data for SO3 come from?
SO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a fundamental inorganic oxide, sulfur trioxide stands as a critical reference point for sulfur-based chemistry. Unlike many transient or metastable oxides, its position on the thermodynamic convex hull ensures its reliability as a chemical building block in industrial applications.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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