RuO2

Ruthenium dioxide · Ruthenium(IV) oxide

Ruthenium dioxide is a metallic-looking inorganic compound known for its high electrical conductivity and chemical stability. It is widely utilized as a catalyst in various electrochemical processes and as a conductive coating in electronic components.

Crystal structure of RuO2 (tetragonal, P42/mnm (No. 136))
Ground-state structure · Materials Project
Overview

Key Properties

Cross-validated computational properties for Ruthenium dioxide, aggregated across 3 databases.

Band Gap

0.61 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

217
3 databases, 33 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for RuO2, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P42/mnm (No. 136)tetragonal0.000.0000-7.8487.07
Pa-3 (No. 205)cubic0.000.0648-7.7837.78
Fm-3m (No. 225)cubic0.610.1881-7.6607.71
P1 (No. 1)Triclinic5.68
P1 (No. 1)Triclinic6.07
P-1 (No. 2)Triclinic4.06
Fmmm (No. 69)Orthorhombic6.59
I4/mcm (No. 140)Tetragonal8.01
P-1 (No. 2)Triclinic6.04
P-1 (No. 2)Triclinic6.02
C2 (No. 5)Monoclinic6.78
P1 (No. 1)Triclinic5.16
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting RuO2.

Sol-Gel
Procedure available · ceder_solid_state
Uses

Applications

Where Ruthenium dioxide is used.

ElectrocatalysisSupercapacitorsResistorsChlor-alkali process electrodes
Reference

Frequently Asked Questions

Common questions about Ruthenium dioxide, answered from cross-validated data.

What is RuO2?

Ruthenium dioxide is a metallic-looking inorganic compound known for its high electrical conductivity and chemical stability. It is widely utilized as a catalyst in various electrochemical processes and as a conductive coating in electronic components.

More questions
What is RuO2 used for?
Ruthenium dioxide (RuO2) is used in electrocatalysis, supercapacitors, resistors, and chlor-alkali process electrodes.
What is the band gap of RuO2?
Ruthenium dioxide (RuO2) has a DFT-computed band gap of 0.61 eV across 217 reported structures.
Is RuO2 a metal, semiconductor, or insulator?
With a band gap up to 0.61 eV it is a semiconductor.
Is RuO2 thermodynamically stable?
Yes — Ruthenium dioxide (RuO2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
What is the crystal structure of RuO2?
The lowest-energy reported polymorph of Ruthenium dioxide (RuO2) is tetragonal symmetry, space group P42/mnm (No. 136).
What is the density of RuO2?
The computed density of the ground-state structure of Ruthenium dioxide (RuO2) is 7.07 g/cm³.
How many polymorphs of RuO2 are known?
217 structures of RuO2 are reported across 3 databases, spanning 33 distinct space groups.
How is RuO2 synthesized?
Literature-reported routes for RuO2 include sol-gel.
What elements does RuO2 contain?
Ruthenium dioxide (RuO2) contains O and Ru (2 elements).
Where does the data for RuO2 come from?
RuO2 data is cross-referenced from materials_project, mpaloe.
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Related Compounds

Other Oxide Oxygen-Evolution Catalysts in the database.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.

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