PtI4

Platinum tetraiodide · Platinum(IV) iodide

Platinum tetraiodide is a stable, semiconducting platinum halide used primarily as a chemical precursor in catalytic and synthetic applications.

Crystal structure of PtI4
Ground-state structure · Materials Project
Overview

About Platinum tetraiodide

Platinum tetraiodide is a thermodynamically stable compound that sits on the convex hull, indicating significant structural robustness. As a semiconducting member of the platinum-group halide family, it serves as a critical precursor for various chemical transformations and material synthesis pathways.

Its unique electronic properties make it a subject of interest for researchers exploring advanced catalytic materials. By leveraging the stability of the platinum-iodine framework, this compound facilitates precise chemical reactions in specialized industrial and laboratory environments.

At a glance

Key Properties

Cross-validated computational properties for Platinum tetraiodide, aggregated across 2 databases.

Band Gap

0.73 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
1 DFT source

Structures

16
2 databases, 7 space groups
Uses

Applications

Where Platinum tetraiodide is used.

Chemical synthesisCatalytic precursorMaterials science research
Reference

Frequently Asked Questions

Common questions about Platinum tetraiodide, answered from cross-validated data.

What is PtI4?

Platinum tetraiodide is a stable, semiconducting platinum halide used primarily as a chemical precursor in catalytic and synthetic applications.

More questions
What is PtI4 used for?
Platinum tetraiodide (PtI4) is used in chemical synthesis, catalytic precursor, and materials science research.
What is the band gap of PtI4?
Platinum tetraiodide (PtI4) has a DFT-computed band gap of 0.73 eV across 16 reported structures.
Is PtI4 a metal, semiconductor, or insulator?
With a band gap up to 0.73 eV it is a semiconductor.
Is PtI4 thermodynamically stable?
Yes — Platinum tetraiodide (PtI4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of PtI4 are known?
16 structures of PtI4 are reported across 2 databases, spanning 7 distinct space groups.
What elements does PtI4 contain?
Platinum tetraiodide (PtI4) contains I and Pt (2 elements).
Where does the data for PtI4 come from?
PtI4 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the platinum-group alloy catalysts class.

Unlike the metallic or intermetallic nature of siblings such as LaRh or BaPd, platinum tetraiodide is distinguished by its semiconducting electronic character and halide-based chemistry. While many platinum-group alloys like As2Pt focus on structural metallic bonding, this compound utilizes its oxidation state to drive specific reactivity, setting it apart from the more traditional alloy-based members of its class.

Explore

Related Compounds

Other Platinum-Group Alloy Catalysts in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze PtI4 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →