PtCN

PtCN is a semiconducting platinum-carbon-nitrogen compound that exists as a metastable phase in materials research.

CNPt
Overview

About PtCN

PtCN is a platinum-based compound featuring carbon and nitrogen, characterized by its semiconducting electronic nature. Its structural complexity is highlighted by a diverse range of reported configurations across crystalline databases.

Due to its position relative to the thermodynamic ground state, this material is considered metastable. Research into this compound focuses on understanding its unique bonding environment and potential for synthesis under specialized conditions.

At a glance

Key Properties

Cross-validated computational properties for PtCN, aggregated across 2 databases.

Band Gap

1.78 eV
Range across DFT structures

Energy Above Hull

0.437 eV/atom
Best (lowest) across sources

Stability

Above hull
1 DFT source

Structures

19
2 databases, 7 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for PtCN, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
I-42d (No. 122)tetragonal1.780.4366-17.4917.51
P-1 (No. 2)Triclinic9.79
P-1 (No. 2)Triclinic10.14
C2/m (No. 12)Monoclinic14.13
Pmmn (No. 59)Orthorhombic11.54
Pmmn (No. 59)Orthorhombic14.38
P-1 (No. 2)Triclinic9.43
P-1 (No. 2)Triclinic9.73
C2/m (No. 12)Monoclinic11.22
P-1 (No. 2)Triclinic11.79
Pmm2 (No. 25)Orthorhombic11.74
P21/m (No. 11)Monoclinic14.89
Reference

Frequently Asked Questions

Common questions about PtCN, answered from cross-validated data.

What is PtCN?

PtCN is a semiconducting platinum-carbon-nitrogen compound that exists as a metastable phase in materials research.

More questions
What is the band gap of PtCN?
PtCN has a DFT-computed band gap of 1.78 eV across 19 reported structures.
Is PtCN a metal, semiconductor, or insulator?
With a band gap up to 1.78 eV it is a semiconductor.
Is PtCN thermodynamically stable?
PtCN has a lowest energy above hull of 0.437 eV/atom (above hull).
What is the crystal structure of PtCN?
The lowest-energy reported polymorph of PtCN is tetragonal symmetry, space group I-42d (No. 122).
What is the density of PtCN?
The computed density of the ground-state structure of PtCN is 7.51 g/cm³.
How many polymorphs of PtCN are known?
19 structures of PtCN are reported across 2 databases, spanning 7 distinct space groups.
What elements does PtCN contain?
PtCN contains C, N, and Pt (3 elements).
Where does the data for PtCN come from?
PtCN data is cross-referenced from materials_project, mpaloe.
Comparison

How It Compares

As a unique platinum-carbon-nitrogen system, PtCN occupies a distinct niche in materials research. Without direct structural analogs in its immediate class, it serves as an important case study for exploring the limits of platinum-based coordination chemistry and the stability of metal-cyanide-like frameworks.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.

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