PbCl2

Lead(II) chloride · cotunnite

Lead(II) chloride is a stable, insulating inorganic salt frequently used as a primary starting material in chemical synthesis and industrial applications.

ClPb
Crystal structure of PbCl2
Ground-state structure · Materials Project
Overview

About Lead(II) chloride

Lead(II) chloride is a thermodynamically stable inorganic compound that exists as a wide-gap insulator. It is characterized by its significant structural versatility, as evidenced by the large number of reported crystalline arrangements found in materials databases.

This compound serves as a critical precursor in the synthesis of various lead-based materials and organometallic compounds. Its stability and distinct electronic profile make it a foundational subject for studies in solid-state chemistry and materials science.

At a glance

Key Properties

Cross-validated computational properties for Lead(II) chloride, aggregated across 4 databases.

Band Gap

2.94–3.79 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

48
4 databases, 13 space groups
Uses

Applications

Where Lead(II) chloride is used.

Precursor for organometallic compoundsFlux in metal refiningComponent in specialized glass manufacturingInfrared optical materials
Intellectual Property

Patent Landscape

1 patent reference PbCl2 or close compositional variants.

PatentTitleAssigneeGranted
4510220Cell with PbCl.sub.2 cathode
Reference

Frequently Asked Questions

Common questions about Lead(II) chloride, answered from cross-validated data.

What is PbCl2?

Lead(II) chloride is a stable, insulating inorganic salt frequently used as a primary starting material in chemical synthesis and industrial applications.

More questions
What is PbCl2 used for?
Lead(II) chloride (PbCl2) is used in precursor for organometallic compounds, flux in metal refining, component in specialized glass manufacturing, and infrared optical materials.
What is the band gap of PbCl2?
Lead(II) chloride (PbCl2) has a DFT-computed band gap of 2.94–3.79 eV across 48 reported structures.
Is PbCl2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.79 eV it is an insulator / wide-band-gap material.
Is PbCl2 thermodynamically stable?
Yes — Lead(II) chloride (PbCl2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of PbCl2 are known?
48 structures of PbCl2 are reported across 4 databases, spanning 13 distinct space groups.
What elements does PbCl2 contain?
Lead(II) chloride (PbCl2) contains Cl and Pb (2 elements).
Where does the data for PbCl2 come from?
PbCl2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a highly stable and well-documented material, lead(II) chloride represents a benchmark for lead halide systems. It occupies a prominent role in its class due to its extensive structural data and established utility in chemical manufacturing.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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