PPb

PPb is a metastable, metallic binary compound of phosphorus and lead that exhibits significant structural diversity.

PPb
Crystal structure of PPb
Ground-state structure · Materials Project
Overview

About PPb

PPb is a binary compound composed of phosphorus and lead that exhibits metallic electronic behavior. Its structural landscape is notably diverse, with a high number of reported configurations across various databases, highlighting the complexity of its bonding environment.

As a material that sits above the thermodynamic stability hull, PPb represents a metastable phase that challenges conventional synthesis pathways. Its metallic nature and structural variety make it a compelling subject for researchers investigating the limits of phosphorus-lead chemical bonding.

At a glance

Key Properties

Cross-validated computational properties for PPb, aggregated across 4 databases.

Band Gap

Metallic / not reported

Energy Above Hull

0.144 eV/atom
Best (lowest) across sources

Stability

Above hull
3 DFT sources

Structures

45
4 databases, 12 space groups
Reference

Frequently Asked Questions

Common questions about PPb, answered from cross-validated data.

What is PPb?

PPb is a metastable, metallic binary compound of phosphorus and lead that exhibits significant structural diversity.

More questions
What is the band gap of PPb?
PPb is computed to be metallic (no band gap) in the reported DFT structures.
Is PPb a metal, semiconductor, or insulator?
Computed band structures report no gap, so it is metallic.
Is PPb thermodynamically stable?
PPb has a lowest energy above hull of 0.144 eV/atom (above hull).
How many polymorphs of PPb are known?
45 structures of PPb are reported across 4 databases, spanning 12 distinct space groups.
What elements does PPb contain?
PPb contains P and Pb (2 elements).
Where does the data for PPb come from?
PPb data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique binary system without direct structural analogues in this specific dataset, PPb stands as a distinct case study in metastable metallic phosphides, offering a different structural profile compared to more stable, naturally occurring binary compounds.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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