NaSbF6

sodium hexafluoroantimonate · sodium antimonate fluoride

Sodium hexafluoroantimonate is a stable, insulating fluoride salt utilized in advanced electrochemical and chemical synthesis applications.

FNaSb
Crystal structure of NaSbF6
Ground-state structure · Materials Project
Overview

About sodium hexafluoroantimonate

Sodium hexafluoroantimonate is a robust inorganic fluoride compound characterized by its wide-gap insulating electronic structure. As a thermodynamically stable material located on the convex hull, it exhibits significant structural integrity, which is essential for its role in specialized chemical applications. The compound is frequently studied for its chemical stability and its utility as a precursor or electrolyte component in high-performance electrochemical systems. Its predictable behavior under various conditions makes it a reliable candidate for research involving complex fluoride chemistry and ionic transport mechanisms.

At a glance

Key Properties

Cross-validated computational properties for sodium hexafluoroantimonate, aggregated across 3 databases.

Band Gap

4.76–6.12 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

10
3 databases, 2 space groups
Uses

Applications

Where sodium hexafluoroantimonate is used.

Electrochemical electrolytesSpecialty chemical synthesisIonic conductivity research
Reference

Frequently Asked Questions

Common questions about sodium hexafluoroantimonate, answered from cross-validated data.

What is NaSbF6?

Sodium hexafluoroantimonate is a stable, insulating fluoride salt utilized in advanced electrochemical and chemical synthesis applications.

More questions
What is NaSbF6 used for?
sodium hexafluoroantimonate (NaSbF6) is used in electrochemical electrolytes, specialty chemical synthesis, and ionic conductivity research.
What is the band gap of NaSbF6?
sodium hexafluoroantimonate (NaSbF6) has a DFT-computed band gap of 4.76–6.12 eV across 10 reported structures.
Is NaSbF6 a metal, semiconductor, or insulator?
With a wide band gap up to 6.12 eV it is an insulator / wide-band-gap material.
Is NaSbF6 thermodynamically stable?
Yes — sodium hexafluoroantimonate (NaSbF6) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of NaSbF6 are known?
10 structures of NaSbF6 are reported across 3 databases, spanning 2 distinct space groups.
What elements does NaSbF6 contain?
sodium hexafluoroantimonate (NaSbF6) contains F, Na, and Sb (3 elements).
Where does the data for NaSbF6 come from?
NaSbF6 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone member of its chemical class in this context, sodium hexafluoroantimonate serves as a benchmark for stability and insulating performance. Its position on the convex hull underscores its reliability compared to less stable fluoride complexes, establishing it as a foundational material for exploring the broader properties of hexafluoroantimonate salts.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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