NaAsO3

sodium metarsenite · sodium arsenite

NaAsO3 is a stable, semiconducting sodium arsenite compound used as a precursor in chemical synthesis and materials research.

AsNaO
Crystal structure of NaAsO3
Ground-state structure · Materials Project
Overview

About sodium metarsenite

NaAsO3 is a thermodynamically stable inorganic compound characterized by its semiconducting electronic nature. As a member of the arsenite family, it maintains a robust structural framework that has been documented across multiple crystalline arrangements in materials databases. Its stability on the convex hull underscores its significance as a well-defined chemical entity in solid-state chemistry. The compound serves as a critical precursor in various chemical processes, leveraging the reactivity of the arsenite moiety. Its semiconducting properties make it a subject of interest for researchers investigating the intersection of inorganic synthesis and electronic material behavior.

At a glance

Key Properties

Cross-validated computational properties for sodium metarsenite, aggregated across 3 databases.

Band Gap

2.86 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

7
3 databases, 3 space groups
Uses

Applications

Where sodium metarsenite is used.

Chemical synthesisMaterials science researchPrecursor for arsenic-based compounds
Reference

Frequently Asked Questions

Common questions about sodium metarsenite, answered from cross-validated data.

What is NaAsO3?

NaAsO3 is a stable, semiconducting sodium arsenite compound used as a precursor in chemical synthesis and materials research.

More questions
What is NaAsO3 used for?
sodium metarsenite (NaAsO3) is used in chemical synthesis, materials science research, and precursor for arsenic-based compounds.
What is the band gap of NaAsO3?
sodium metarsenite (NaAsO3) has a DFT-computed band gap of 2.86 eV across 7 reported structures.
Is NaAsO3 a metal, semiconductor, or insulator?
With a band gap up to 2.86 eV it is a semiconductor.
Is NaAsO3 thermodynamically stable?
Yes — sodium metarsenite (NaAsO3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of NaAsO3 are known?
7 structures of NaAsO3 are reported across 3 databases, spanning 3 distinct space groups.
What elements does NaAsO3 contain?
sodium metarsenite (NaAsO3) contains As, Na, and O (3 elements).
Where does the data for NaAsO3 come from?
NaAsO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a stable arsenite, NaAsO3 occupies a distinct position in inorganic chemistry, serving as a foundational material for understanding the structural behavior of alkali metal arsenites. Without direct structural analogs in this specific classification, it stands as a primary reference point for studying the coordination environments and electronic characteristics of arsenic-oxygen frameworks.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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