NaAsO2

Sodium arsenite · Sodium metaarsenite

Sodium arsenite is a stable, insulating inorganic compound widely used as a chemical reagent and industrial intermediate.

AsNaO
Crystal structure of NaAsO2
Ground-state structure · Materials Project
Overview

About Sodium arsenite

Sodium arsenite is a stable inorganic compound that exists as a wide-band-gap insulator. Its presence on the convex hull confirms its thermodynamic stability, making it a reliable subject for structural studies across multiple databases. The compound serves as a critical chemical intermediate. Due to its distinct electronic character, it is primarily utilized in specialized industrial applications and as a precursor in chemical synthesis processes.

At a glance

Key Properties

Cross-validated computational properties for Sodium arsenite, aggregated across 4 databases.

Band Gap

3.63–3.74 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

11
4 databases, 3 space groups
Uses

Applications

Where Sodium arsenite is used.

Chemical synthesisHerbicide productionPreservative agentAnalytical chemistry reagent
Reference

Frequently Asked Questions

Common questions about Sodium arsenite, answered from cross-validated data.

What is NaAsO2?

Sodium arsenite is a stable, insulating inorganic compound widely used as a chemical reagent and industrial intermediate.

More questions
What is NaAsO2 used for?
Sodium arsenite (NaAsO2) is used in chemical synthesis, herbicide production, preservative agent, and analytical chemistry reagent.
What is the band gap of NaAsO2?
Sodium arsenite (NaAsO2) has a DFT-computed band gap of 3.63–3.74 eV across 11 reported structures.
Is NaAsO2 a metal, semiconductor, or insulator?
With a wide band gap up to 3.74 eV it is an insulator / wide-band-gap material.
Is NaAsO2 thermodynamically stable?
Yes — Sodium arsenite (NaAsO2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of NaAsO2 are known?
11 structures of NaAsO2 are reported across 4 databases, spanning 3 distinct space groups.
What elements does NaAsO2 contain?
Sodium arsenite (NaAsO2) contains As, Na, and O (3 elements).
Where does the data for NaAsO2 come from?
NaAsO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone compound in this context, sodium arsenite represents a fundamental inorganic salt characterized by its high thermodynamic stability and insulating electronic nature, serving as a benchmark for arsenic-based sodium compounds.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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