Mg3Sb2

magnesium antimonide · trimagnesium diantimonide

Magnesium antimonide is a stable, semiconducting binary compound used in materials research for its well-defined structural properties.

MgSb
Crystal structure of Mg3Sb2
Ground-state structure · Materials Project
Overview

About magnesium antimonide

Magnesium antimonide is a binary intermetallic compound characterized by its semiconducting electronic nature. As a material that sits on the convex hull, it exhibits significant thermodynamic stability, making it a robust candidate for research into solid-state materials. Its structural diversity is well-documented, with numerous reported configurations across various databases.

This compound is of particular interest in materials science due to its favorable electronic properties and stability. It serves as a foundational material for investigating the behavior of magnesium-antimony systems, providing a reliable platform for developing new technologies that rely on stable, semiconducting inorganic frameworks.

At a glance

Key Properties

Cross-validated computational properties for magnesium antimonide, aggregated across 4 databases.

Band Gap

0.22–1.32 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
3 DFT sources

Structures

19
4 databases, 3 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Mg3Sb2.

Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where magnesium antimonide is used.

thermoelectric materials researchsemiconductor device developmentsolid-state physics studies
Reference

Frequently Asked Questions

Common questions about magnesium antimonide, answered from cross-validated data.

What is Mg3Sb2?

Magnesium antimonide is a stable, semiconducting binary compound used in materials research for its well-defined structural properties.

More questions
What is Mg3Sb2 used for?
magnesium antimonide (Mg3Sb2) is used in thermoelectric materials research, semiconductor device development, and solid-state physics studies.
What is the band gap of Mg3Sb2?
magnesium antimonide (Mg3Sb2) has a DFT-computed band gap of 0.22–1.32 eV across 19 reported structures.
Is Mg3Sb2 a metal, semiconductor, or insulator?
With a band gap up to 1.32 eV it is a semiconductor.
Is Mg3Sb2 thermodynamically stable?
Yes — magnesium antimonide (Mg3Sb2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of Mg3Sb2 are known?
19 structures of Mg3Sb2 are reported across 4 databases, spanning 3 distinct space groups.
How is Mg3Sb2 synthesized?
Literature-reported routes for Mg3Sb2 include solid state (8 procedures documented).
What elements does Mg3Sb2 contain?
magnesium antimonide (Mg3Sb2) contains Mg and Sb (2 elements).
Where does the data for Mg3Sb2 come from?
Mg3Sb2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a thermodynamically stable semiconductor, magnesium antimonide represents a benchmark material within its chemical system. It serves as a primary reference point for understanding the phase stability and electronic performance of magnesium-based antimonides, establishing the baseline for how these elements interact to form functional crystalline structures.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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