LiN3
Lithium azide · lithium trinitride
Lithium azide is a stable, insulating inorganic salt frequently utilized as a source of reactive nitrogen in chemical synthesis.
About Lithium azide
Lithium azide is a distinct inorganic compound characterized by its insulating electronic nature and high thermodynamic stability. As a member of the azide family, it serves as a critical nitrogen-rich precursor in various synthetic pathways and energetic material research.
Its structural landscape is remarkably diverse, supported by a vast collection of reported configurations across major materials databases. This extensive data availability underscores its importance as a fundamental subject for studying ionic bonding and nitrogen-based chemistry.
Key Properties
Cross-validated computational properties for Lithium azide, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where Lithium azide is used.
Frequently Asked Questions
Common questions about Lithium azide, answered from cross-validated data.
What is LiN3?
Lithium azide is a stable, insulating inorganic salt frequently utilized as a source of reactive nitrogen in chemical synthesis.
What is LiN3 used for?
What is the band gap of LiN3?
Is LiN3 a metal, semiconductor, or insulator?
Is LiN3 thermodynamically stable?
How many polymorphs of LiN3 are known?
What elements does LiN3 contain?
Where does the data for LiN3 come from?
How It Compares
As a standalone representative of its chemical class in this context, lithium azide serves as a primary reference point for understanding the behavior of alkali metal azides. Its position on the convex hull establishes it as a robust benchmark for evaluating the stability and reactivity of related nitrogen-rich ionic solids.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
Analyze LiN3 in the Lattice Graph platform
Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.
Explore the Platform →