LiF

Lithium fluoride · LiF

Lithium fluoride is a stable, insulating salt used primarily for its exceptional optical transparency and resistance to radiation.

FLi
Crystal structure of LiF
Ground-state structure · Materials Project
Overview

About Lithium fluoride

Lithium fluoride is a simple binary salt that exists as a thermodynamically stable crystal. It is characterized by a wide band gap, classifying it as a highly effective electrical insulator with significant optical transparency across a broad spectrum.

This material is widely utilized in specialized technical fields, particularly where high-energy radiation or ultraviolet light transmission is required. Its structural stability and electronic insulating behavior make it a fundamental component in advanced optical coatings and molten salt reactor technology.

At a glance

Key Properties

Cross-validated computational properties for Lithium fluoride, aggregated across 4 databases.

Band Gap

7.56–8.72 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

187
4 databases, 30 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting LiF.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Lithium fluoride is used.

Optical windows for ultraviolet and infrared transmissionMolten salt reactor fuel carriersRadiation detectorsX-ray monochromators
Intellectual Property

Patent Landscape

4 patents reference LiF or close compositional variants.

PatentTitleAssigneeGranted
9382615Vapor deposition of LiF thin films
7449238LiF-coated doped and undoped yttrium oxide
10644309LiF-embedded SiG powder for lithium ion battery
9909211Vapor deposition of LiF thin films
Reference

Frequently Asked Questions

Common questions about Lithium fluoride, answered from cross-validated data.

What is LiF?

Lithium fluoride is a stable, insulating salt used primarily for its exceptional optical transparency and resistance to radiation.

More questions
What is LiF used for?
Lithium fluoride (LiF) is used in optical windows for ultraviolet and infrared transmission, molten salt reactor fuel carriers, radiation detectors, and x-ray monochromators.
What is the band gap of LiF?
Lithium fluoride (LiF) has a DFT-computed band gap of 7.56–8.72 eV across 187 reported structures.
Is LiF a metal, semiconductor, or insulator?
With a wide band gap up to 8.72 eV it is an insulator / wide-band-gap material.
Is LiF thermodynamically stable?
Yes — Lithium fluoride (LiF) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of LiF are known?
187 structures of LiF are reported across 4 databases, spanning 30 distinct space groups.
How is LiF synthesized?
Literature-reported routes for LiF include sol gel (10 procedures documented).
What elements does LiF contain?
Lithium fluoride (LiF) contains F and Li (2 elements).
Where does the data for LiF come from?
LiF data is cross-referenced from latticegraph.
Comparison

How It Compares

As a fundamental inorganic salt, lithium fluoride serves as a benchmark for wide-gap insulating materials, providing a stable and well-understood structural framework that informs the study of other binary alkali halides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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