LiF
Lithium fluoride · LiF
Lithium fluoride is a stable, insulating salt used primarily for its exceptional optical transparency and resistance to radiation.

About Lithium fluoride
Lithium fluoride is a simple binary salt that exists as a thermodynamically stable crystal. It is characterized by a wide band gap, classifying it as a highly effective electrical insulator with significant optical transparency across a broad spectrum.
This material is widely utilized in specialized technical fields, particularly where high-energy radiation or ultraviolet light transmission is required. Its structural stability and electronic insulating behavior make it a fundamental component in advanced optical coatings and molten salt reactor technology.
Key Properties
Cross-validated computational properties for Lithium fluoride, aggregated across 4 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Synthesis Routes
Literature-extracted synthesis procedures targeting LiF.
Applications
Where Lithium fluoride is used.
Patent Landscape
4 patents reference LiF or close compositional variants.
| Patent | Title | Assignee | Granted |
|---|---|---|---|
| 9382615 | Vapor deposition of LiF thin films | — | — |
| 7449238 | LiF-coated doped and undoped yttrium oxide | — | — |
| 10644309 | LiF-embedded SiG powder for lithium ion battery | — | — |
| 9909211 | Vapor deposition of LiF thin films | — | — |
Frequently Asked Questions
Common questions about Lithium fluoride, answered from cross-validated data.
What is LiF?
Lithium fluoride is a stable, insulating salt used primarily for its exceptional optical transparency and resistance to radiation.
What is LiF used for?
What is the band gap of LiF?
Is LiF a metal, semiconductor, or insulator?
Is LiF thermodynamically stable?
How many polymorphs of LiF are known?
How is LiF synthesized?
What elements does LiF contain?
Where does the data for LiF come from?
How It Compares
As a fundamental inorganic salt, lithium fluoride serves as a benchmark for wide-gap insulating materials, providing a stable and well-understood structural framework that informs the study of other binary alkali halides.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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