Li3V4NiO12
Li3V4NiO12 is a semimetallic layered lithium transition-metal oxide currently being studied for its unique electronic properties and potential applications in advanced energy storage systems.
About Li3V4NiO12
Li3V4NiO12 belongs to the complex family of layered lithium transition-metal oxides. Characterized by a semimetallic electronic nature, this compound represents a unique intersection of vanadium and nickel chemistry within a lithium-rich framework. Its electronic properties suggest potential for specialized charge-transfer applications, though its structural complexity remains a subject of intense investigation.
As a material that sits above the thermodynamic hull, Li3V4NiO12 is considered metastable, which provides researchers with a challenging but intriguing target for synthesis and stability studies. Its existence across multiple databases highlights its importance as a candidate for exploring unconventional pathways in battery electrode development and solid-state ionics.
Key Properties
Cross-validated computational properties for Li3V4NiO12, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where Li3V4NiO12 is used.
Frequently Asked Questions
Common questions about Li3V4NiO12, answered from cross-validated data.
What is Li3V4NiO12?
Li3V4NiO12 is a semimetallic layered lithium transition-metal oxide currently being studied for its unique electronic properties and potential applications in advanced energy storage systems.
What is Li3V4NiO12 used for?
What is the band gap of Li3V4NiO12?
Is Li3V4NiO12 a metal, semiconductor, or insulator?
Is Li3V4NiO12 thermodynamically stable?
How many polymorphs of Li3V4NiO12 are known?
What elements does Li3V4NiO12 contain?
Where does the data for Li3V4NiO12 come from?
How It Compares
Within the layered lithium transition-metal oxides class.
Unlike the highly stable and commercially ubiquitous LiCoO2 or LiNiO2, Li3V4NiO12 exhibits a more complex and potentially unstable structural profile. While standard layered oxides like LiNiO2 are optimized for high-capacity cycling, this compound offers a different electronic landscape due to its semimetallic character, setting it apart from the more traditional insulating or semiconducting members of the lithium transition-metal oxide class.
Related Compounds
Other Layered Lithium Transition-Metal Oxides in the database.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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