Li3Co3SbO8

Li3Co3SbO8 is a semiconducting, metastable layered lithium transition-metal oxide used in advanced materials research.

Crystal structure of Li3Co3SbO8
Ground-state structure · Materials Project
Overview

About Li3Co3SbO8

Li3Co3SbO8 is a complex layered lithium transition-metal oxide characterized by its semiconducting electronic nature. As a metastable phase, it represents a unique structural arrangement within the broader family of lithium-based oxides, offering researchers a distinct platform for studying ion mobility and structural stability in electrochemical systems. Its composition, integrating cobalt and antimony, highlights the diversity possible within oxygen-coordinated transition metal frameworks. This material is primarily of interest in the context of fundamental materials science research, where understanding the interplay between its specific stoichiometry and electronic properties is essential for developing next-generation energy storage components. By investigating metastable oxides like this, scientists can better map the landscape of potential electrode materials that deviate from conventional, highly stable structures.

At a glance

Key Properties

Cross-validated computational properties for Li3Co3SbO8, aggregated across 3 databases.

Band Gap

0.21–0.89 eV
Range across DFT structures

Energy Above Hull

0.090 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

14
3 databases, 2 space groups
Uses

Applications

Where Li3Co3SbO8 is used.

Energy storage researchElectrode material developmentSolid-state chemistry studies
Reference

Frequently Asked Questions

Common questions about Li3Co3SbO8, answered from cross-validated data.

What is Li3Co3SbO8?

Li3Co3SbO8 is a semiconducting, metastable layered lithium transition-metal oxide used in advanced materials research.

More questions
What is Li3Co3SbO8 used for?
Li3Co3SbO8 is used in energy storage research, electrode material development, and solid-state chemistry studies.
What is the band gap of Li3Co3SbO8?
Li3Co3SbO8 has a DFT-computed band gap of 0.21–0.89 eV across 14 reported structures.
Is Li3Co3SbO8 a metal, semiconductor, or insulator?
With a band gap up to 0.89 eV it is a semiconductor.
Is Li3Co3SbO8 thermodynamically stable?
Li3Co3SbO8 has a lowest energy above hull of 0.090 eV/atom (metastable).
How many polymorphs of Li3Co3SbO8 are known?
14 structures of Li3Co3SbO8 are reported across 3 databases, spanning 2 distinct space groups.
What elements does Li3Co3SbO8 contain?
Li3Co3SbO8 contains Co, Li, O, and Sb (4 elements).
Where does the data for Li3Co3SbO8 come from?
Li3Co3SbO8 data is cross-referenced from latticegraph.
Comparison

How It Compares

Within the layered lithium transition-metal oxides class.

Within the expansive class of layered lithium transition-metal oxides, Li3Co3SbO8 occupies a specialized niche compared to well-established commercial standards like LiCoO2. While LiCoO2 is celebrated for its thermodynamic stability and widespread use in battery cathodes, Li3Co3SbO8 presents a more complex, metastable structural profile. It shares the fundamental layered motif found in materials like LiNiO2 and LiMnO2, yet its inclusion of antimony suggests a different approach to tuning the electronic environment of the transition metal layer, distinguishing it from the simpler binary or ternary oxides in the group.

Explore

Related Compounds

Other Layered Lithium Transition-Metal Oxides in the database.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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