KO3

potassium ozonide · potassium trioxide

Potassium ozonide is a metastable, semiconducting inorganic compound primarily recognized for its role as a reactive oxygen source.

KO
Crystal structure of KO3
Ground-state structure · Materials Project
Overview

About potassium ozonide

Potassium ozonide is a unique inorganic compound characterized by its semiconducting electronic nature. As a metastable species, it represents a reactive and highly specific chemical state within the potassium-oxygen system, drawing significant interest for its complex structural chemistry.

Its importance lies in its role as a powerful oxidizing agent and a potential source of reactive oxygen species. Researchers study this compound to better understand the stability of higher-order oxides and their behavior in controlled chemical environments.

At a glance

Key Properties

Cross-validated computational properties for potassium ozonide, aggregated across 3 databases.

Band Gap

0.41–0.87 eV
Range across DFT structures

Energy Above Hull

0.093 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

43
3 databases, 10 space groups
Uses

Applications

Where potassium ozonide is used.

chemical oxygen generationspecialized oxidizing agentsfundamental chemical research
Reference

Frequently Asked Questions

Common questions about potassium ozonide, answered from cross-validated data.

What is KO3?

Potassium ozonide is a metastable, semiconducting inorganic compound primarily recognized for its role as a reactive oxygen source.

More questions
What is KO3 used for?
potassium ozonide (KO3) is used in chemical oxygen generation, specialized oxidizing agents, and fundamental chemical research.
What is the band gap of KO3?
potassium ozonide (KO3) has a DFT-computed band gap of 0.41–0.87 eV across 43 reported structures.
Is KO3 a metal, semiconductor, or insulator?
With a band gap up to 0.87 eV it is a semiconductor.
Is KO3 thermodynamically stable?
potassium ozonide (KO3) has a lowest energy above hull of 0.093 eV/atom (metastable).
How many polymorphs of KO3 are known?
43 structures of KO3 are reported across 3 databases, spanning 10 distinct space groups.
What elements does KO3 contain?
potassium ozonide (KO3) contains K and O (2 elements).
Where does the data for KO3 come from?
KO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a distinct member of the alkali metal ozonide family, this compound occupies a specialized niche where structural metastability dictates its reactivity. Unlike more common, highly stable binary oxides, it requires precise conditions to maintain its integrity, serving as a critical subject for fundamental studies on oxygen-rich inorganic frameworks.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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