KHCO2

potassium formate · potassium methanoate

Potassium formate is a metastable, insulating salt used primarily as a chemical intermediate and industrial reagent.

CHKO
Crystal structure of KHCO2
Ground-state structure · Materials Project
Overview

About potassium formate

Potassium formate is a crystalline salt that functions as an insulating, wide-gap material. It exists in a metastable state, requiring specific conditions for synthesis and preservation, which is reflected in the diverse structural data available for this compound across material databases. Its chemical nature as a formate salt makes it a versatile reagent in various industrial processes. It is particularly valued in sectors where its solubility and chemical reactivity can be leveraged for specialized synthesis or as a functional additive.

At a glance

Key Properties

Cross-validated computational properties for potassium formate, aggregated across 3 databases.

Band Gap

3.15–4.33 eV
Range across DFT structures

Energy Above Hull

0.047 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

6
3 databases, 2 space groups
Uses

Applications

Where potassium formate is used.

de-icing agentdrilling fluid additivechemical synthesis intermediateheat transfer fluid
Reference

Frequently Asked Questions

Common questions about potassium formate, answered from cross-validated data.

What is KHCO2?

Potassium formate is a metastable, insulating salt used primarily as a chemical intermediate and industrial reagent.

More questions
What is KHCO2 used for?
potassium formate (KHCO2) is used in de-icing agent, drilling fluid additive, chemical synthesis intermediate, and heat transfer fluid.
What is the band gap of KHCO2?
potassium formate (KHCO2) has a DFT-computed band gap of 3.15–4.33 eV across 6 reported structures.
Is KHCO2 a metal, semiconductor, or insulator?
With a wide band gap up to 4.33 eV it is an insulator / wide-band-gap material.
Is KHCO2 thermodynamically stable?
potassium formate (KHCO2) has a lowest energy above hull of 0.047 eV/atom (metastable).
How many polymorphs of KHCO2 are known?
6 structures of KHCO2 are reported across 3 databases, spanning 2 distinct space groups.
What elements does KHCO2 contain?
potassium formate (KHCO2) contains C, H, K, and O (4 elements).
Where does the data for KHCO2 come from?
KHCO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone compound in this context, potassium formate serves as a primary example of a metastable formate salt. Its insulating electronic character distinguishes it from more conductive or metallic salts, positioning it as a specialized material for applications requiring stable, non-conductive chemical precursors.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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