KClO4

Potassium perchlorate · Perchloric acid potassium salt

Potassium perchlorate is a stable, insulating salt frequently used as a powerful oxidizer in fireworks, explosives, and rocket propellants.

ClKO
Crystal structure of KClO4
Ground-state structure · Materials Project
Overview

About Potassium perchlorate

Potassium perchlorate is a robust, thermodynamically stable inorganic salt that functions as a wide-gap insulator. Its structural integrity is well-documented, with numerous reported crystalline arrangements that underscore its reliability in chemical applications.

Because of its ability to act as a potent oxygen donor, this compound is essential in industries requiring controlled combustion. Its stability under ambient conditions makes it a preferred choice for high-energy formulations where safety and predictability are paramount.

At a glance

Key Properties

Cross-validated computational properties for Potassium perchlorate, aggregated across 3 databases.

Band Gap

5.14–5.56 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

9
3 databases, 2 space groups
Uses

Applications

Where Potassium perchlorate is used.

PyrotechnicsRocket propellantsExplosivesAnalytical chemistry reagents
Reference

Frequently Asked Questions

Common questions about Potassium perchlorate, answered from cross-validated data.

What is KClO4?

Potassium perchlorate is a stable, insulating salt frequently used as a powerful oxidizer in fireworks, explosives, and rocket propellants.

More questions
What is KClO4 used for?
Potassium perchlorate (KClO4) is used in pyrotechnics, rocket propellants, explosives, and analytical chemistry reagents.
What is the band gap of KClO4?
Potassium perchlorate (KClO4) has a DFT-computed band gap of 5.14–5.56 eV across 9 reported structures.
Is KClO4 a metal, semiconductor, or insulator?
With a wide band gap up to 5.56 eV it is an insulator / wide-band-gap material.
Is KClO4 thermodynamically stable?
Yes — Potassium perchlorate (KClO4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of KClO4 are known?
9 structures of KClO4 are reported across 3 databases, spanning 2 distinct space groups.
What elements does KClO4 contain?
Potassium perchlorate (KClO4) contains Cl, K, and O (3 elements).
Where does the data for KClO4 come from?
KClO4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a prominent inorganic perchlorate, this compound serves as a benchmark for stability and performance within its chemical class, setting the standard for how alkali metal perchlorates behave in energetic applications.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze KClO4 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →