KClO2

potassium chlorite · potassium chlorite

Potassium chlorite is a semiconducting inorganic salt that exists in a metastable state.

ClKO
Crystal structure of KClO2
Ground-state structure · Materials Project
Overview

About potassium chlorite

Potassium chlorite is a semiconducting compound composed of potassium, chlorine, and oxygen. It represents a specific chemical arrangement within the broader family of chlorite salts, characterized by its distinct electronic behavior.

Due to its position relative to the thermodynamic hull, this material is considered metastable. Its structural diversity is highlighted by multiple reported configurations across various databases, making it a subject of interest for researchers studying the stability of oxyhalide systems.

At a glance

Key Properties

Cross-validated computational properties for potassium chlorite, aggregated across 4 databases.

Band Gap

2.31 eV
Range across DFT structures

Energy Above Hull

0.338 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

10
4 databases, 6 space groups
Uses

Applications

Where potassium chlorite is used.

chemical researchmaterials science studies
Reference

Frequently Asked Questions

Common questions about potassium chlorite, answered from cross-validated data.

What is KClO2?

Potassium chlorite is a semiconducting inorganic salt that exists in a metastable state.

More questions
What is KClO2 used for?
potassium chlorite (KClO2) is used in chemical research and materials science studies.
What is the band gap of KClO2?
potassium chlorite (KClO2) has a DFT-computed band gap of 2.31 eV across 10 reported structures.
Is KClO2 a metal, semiconductor, or insulator?
With a band gap up to 2.31 eV it is a semiconductor.
Is KClO2 thermodynamically stable?
potassium chlorite (KClO2) has a lowest energy above hull of 0.338 eV/atom (above hull).
How many polymorphs of KClO2 are known?
10 structures of KClO2 are reported across 4 databases, spanning 6 distinct space groups.
What elements does KClO2 contain?
potassium chlorite (KClO2) contains Cl, K, and O (3 elements).
Where does the data for KClO2 come from?
KClO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a representative of the chlorite class, potassium chlorite serves as a fundamental case study for understanding the structural and electronic trends of alkali metal chlorites. It provides a baseline for evaluating the stability and semiconducting nature of similar oxygen-rich chlorine compounds.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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