KC

KC is an insulating, metastable binary compound of potassium and carbon that exists in a variety of structural forms.

CK
Crystal structure of KC
Ground-state structure · Materials Project
Overview

About KC

KC is a binary compound composed of potassium and carbon. It is notable for its wide-band-gap insulating nature, which distinguishes it from more common conductive carbon-based materials or metallic alloys. The material exhibits significant structural complexity, with numerous reported configurations across various databases.

Due to its position above the thermodynamic stability hull, KC is generally considered an unstable phase under standard conditions. This metastability makes it a subject of interest for researchers studying high-pressure synthesis or unconventional bonding environments where such configurations might be stabilized.

At a glance

Key Properties

Cross-validated computational properties for KC, aggregated across 4 databases.

Band Gap

0.58–3.27 eV
Range across DFT structures

Energy Above Hull

0.266 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

18
4 databases, 7 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting KC.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where KC is used.

Fundamental materials science researchHigh-pressure phase exploration
Reference

Frequently Asked Questions

Common questions about KC, answered from cross-validated data.

What is KC?

KC is an insulating, metastable binary compound of potassium and carbon that exists in a variety of structural forms.

More questions
What is KC used for?
KC is used in fundamental materials science research and high-pressure phase exploration.
What is the band gap of KC?
KC has a DFT-computed band gap of 0.58–3.27 eV across 18 reported structures.
Is KC a metal, semiconductor, or insulator?
With a wide band gap up to 3.27 eV it is an insulator / wide-band-gap material.
Is KC thermodynamically stable?
KC has a lowest energy above hull of 0.266 eV/atom (above hull).
How many polymorphs of KC are known?
18 structures of KC are reported across 4 databases, spanning 7 distinct space groups.
How is KC synthesized?
Literature-reported routes for KC include sol gel, solid state (10 procedures documented).
What elements does KC contain?
KC contains C and K (2 elements).
Where does the data for KC come from?
KC data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique phase within the potassium-carbon system, KC represents a distinct structural arrangement that does not fall into the typical categories of graphite intercalation compounds. It serves as a specialized case study for understanding the limits of stoichiometry and structural stability in alkali-metal carbon systems.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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