KBrF4
potassium tetrafluorobromate · potassium bromotetrafluoride
Potassium tetrafluorobromate is a stable, insulating salt used primarily as a specialized fluorinating agent in chemical synthesis.
About potassium tetrafluorobromate
Potassium tetrafluorobromate is a distinct inorganic salt characterized by its wide-gap insulating electronic structure. As a thermodynamically stable compound residing on the convex hull, it demonstrates structural robustness that makes it a reliable reagent in chemical synthesis. Its ability to act as a potent fluorinating agent stems from the reactive nature of the bromotetrafluoride anion coupled with the stabilizing influence of the potassium cation. This compound is primarily utilized in specialized laboratory settings where controlled fluorination is required for the synthesis of complex materials or organic derivatives. Its stability profile allows for handling in controlled environments, facilitating its role as a key intermediate in halogen chemistry.
Key Properties
Cross-validated computational properties for potassium tetrafluorobromate, aggregated across 3 databases.
Band GapEnergy needed to move an electron from the valence band to the conduction band. Lower or zero values tend to behave more metallic; larger gaps are more insulating or semiconducting.
Energy Above HullThermodynamic distance from the most stable set of competing phases. 0 eV/atom is on the convex hull; small positive values may still be experimentally accessible.
StabilityA plain-language summary of the best reported energy-above-hull result. It reflects whether the lowest-energy structure is on, near, or far from the stability hull.
StructuresCount of reported calculated crystal structures for this formula, including alternate polymorphs, source databases, and observed space groups.
Applications
Where potassium tetrafluorobromate is used.
Frequently Asked Questions
Common questions about potassium tetrafluorobromate, answered from cross-validated data.
What is KBrF4?
Potassium tetrafluorobromate is a stable, insulating salt used primarily as a specialized fluorinating agent in chemical synthesis.
What is KBrF4 used for?
What is the band gap of KBrF4?
Is KBrF4 a metal, semiconductor, or insulator?
Is KBrF4 thermodynamically stable?
How many polymorphs of KBrF4 are known?
What elements does KBrF4 contain?
Where does the data for KBrF4 come from?
How It Compares
As a standalone member of its specific chemical class within this database, potassium tetrafluorobromate serves as a primary reference point for stable, insulating bromofluoride salts. Its position on the convex hull establishes it as a benchmark for thermodynamic stability compared to less stable halogenated complexes, providing a foundational example of how alkali metal cations effectively stabilize complex polyatomic anions.
Data sources & attribution
- latticegraph — Lattice Graph Materials Intelligence Platform
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