K2SO3

Potassium sulfite · Dipotassium sulfite

Potassium sulfite is an insulating, metastable sulfur-containing salt used primarily as a chemical reagent and preservative.

KOS
Crystal structure of K2SO3
Ground-state structure · Materials Project
Overview

About Potassium sulfite

Potassium sulfite is a sulfur-based inorganic compound characterized by its wide-gap insulating electronic structure. As a metastable material, it exhibits distinct reactivity patterns that make it a significant subject for chemical synthesis and structural investigation. Its chemical behavior is driven by the sulfite anion, which plays a central role in its ability to participate in various redox reactions. The compound is frequently utilized in industrial processes where controlled sulfur delivery is required, leveraging its solubility and chemical stability profile. Its presence in multiple structural forms highlights the complexity of its crystalline arrangement, which is of ongoing interest to materials scientists studying alkali metal oxoanions.

At a glance

Key Properties

Cross-validated computational properties for Potassium sulfite, aggregated across 4 databases.

Band Gap

4.91 eV
Range across DFT structures

Energy Above Hull

0.069 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

7
4 databases, 3 space groups
Uses

Applications

Where Potassium sulfite is used.

Food preservativePhotographic developerReducing agent in chemical synthesisWater treatment
Reference

Frequently Asked Questions

Common questions about Potassium sulfite, answered from cross-validated data.

What is K2SO3?

Potassium sulfite is an insulating, metastable sulfur-containing salt used primarily as a chemical reagent and preservative.

More questions
What is K2SO3 used for?
Potassium sulfite (K2SO3) is used in food preservative, photographic developer, reducing agent in chemical synthesis, and water treatment.
What is the band gap of K2SO3?
Potassium sulfite (K2SO3) has a DFT-computed band gap of 4.91 eV across 7 reported structures.
Is K2SO3 a metal, semiconductor, or insulator?
With a wide band gap up to 4.91 eV it is an insulator / wide-band-gap material.
Is K2SO3 thermodynamically stable?
Potassium sulfite (K2SO3) has a lowest energy above hull of 0.069 eV/atom (metastable).
How many polymorphs of K2SO3 are known?
7 structures of K2SO3 are reported across 4 databases, spanning 3 distinct space groups.
What elements does K2SO3 contain?
Potassium sulfite (K2SO3) contains K, O, and S (3 elements).
Where does the data for K2SO3 come from?
K2SO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a standalone member of its chemical class in this context, potassium sulfite serves as a fundamental reference point for understanding the behavior of alkali metal sulfites. Its metastable nature and insulating character distinguish it from more stable or conductive sulfur-containing salts, positioning it as a specialized reagent for applications requiring specific chemical reactivity rather than structural robustness.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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