K2O2

Potassium peroxide · Potassium superoxide

Potassium peroxide is a stable, semiconducting inorganic compound primarily utilized as a specialized chemical reagent.

KO
Crystal structure of K2O2
Ground-state structure · Materials Project
Overview

About Potassium peroxide

Potassium peroxide is a thermodynamically stable compound that sits firmly on the convex hull, indicating significant structural integrity. As a semiconducting material, it exhibits distinct electronic properties that differentiate it from more common ionic oxides, making it a subject of interest in inorganic synthesis and chemical research.

With a high volume of reported structures across major databases, this compound is well-characterized for its role in reactive chemical environments. Its ability to participate in specific redox processes makes it a valuable reagent in laboratory settings where controlled oxidation is required.

At a glance

Key Properties

Cross-validated computational properties for Potassium peroxide, aggregated across 4 databases.

Band Gap

2.08–2.36 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

191
4 databases, 33 space groups
Uses

Applications

Where Potassium peroxide is used.

Chemical synthesisLaboratory oxidation reagentOxygen generation research
Reference

Frequently Asked Questions

Common questions about Potassium peroxide, answered from cross-validated data.

What is K2O2?

Potassium peroxide is a stable, semiconducting inorganic compound primarily utilized as a specialized chemical reagent.

More questions
What is K2O2 used for?
Potassium peroxide (K2O2) is used in chemical synthesis, laboratory oxidation reagent, and oxygen generation research.
What is the band gap of K2O2?
Potassium peroxide (K2O2) has a DFT-computed band gap of 2.08–2.36 eV across 191 reported structures.
Is K2O2 a metal, semiconductor, or insulator?
With a band gap up to 2.36 eV it is a semiconductor.
Is K2O2 thermodynamically stable?
Yes — Potassium peroxide (K2O2) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of K2O2 are known?
191 structures of K2O2 are reported across 4 databases, spanning 33 distinct space groups.
What elements does K2O2 contain?
Potassium peroxide (K2O2) contains K and O (2 elements).
Where does the data for K2O2 come from?
K2O2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a stable member of the alkali metal peroxide family, this compound serves as a fundamental reference point for understanding the electronic and structural behavior of group one peroxides.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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