H2S

Hydrogen sulfide · Sulfuretted hydrogen, Hydrosulfuric acid, Dihydrogen monosulfide

Hydrogen sulfide is a stable, wide-gap insulating gas known for its characteristic odor and its importance as a precursor in chemical manufacturing.

HS
Crystal structure of H2S
Ground-state structure · Materials Project
Overview

About Hydrogen sulfide

Hydrogen sulfide is a colorless, volatile chalcogen hydride that exists as a thermodynamically stable compound. Its electronic character as a wide-gap insulator distinguishes it from more metallic or semi-metallic sulfur-based systems, making it a subject of significant interest in high-pressure physics and chemical research.

With a vast array of reported structures across multiple databases, this compound serves as a fundamental building block in sulfur chemistry. It is widely recognized for its distinct odor and its critical role as a precursor in the production of elemental sulfur and various organosulfur compounds.

At a glance

Key Properties

Cross-validated computational properties for Hydrogen sulfide, aggregated across 5 databases.

Band Gap

3.52–4.43 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
4 DFT sources

Structures

168
5 databases, 30 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting H2S.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where Hydrogen sulfide is used.

Production of elemental sulfurSynthesis of organosulfur compoundsAnalytical chemistry reagentHeavy water production
Intellectual Property

Patent Landscape

50 patents reference H2S or close compositional variants.

PatentTitleAssigneeGranted
11014808System for generating H2S in an alkaline medium and method of using the same
9840675System and method for recovering gas containing CO2 and H2S
11185887Acoustic wave H2S sensor comprising a polymer film comprising carboxylate functional groups and lead or zinc c
10960346Composite amine absorbing solution, and device and method for removing CO2 or H2S or both
9731974Integrated process to recover high quality native CO2 from a sour gas comprising H2S and CO2
7108842Process for the catalytic partial oxidation of H2S using staged addition of oxygen
8501149H2S conversion to sulfur using a regenerated iodine solution
9901875Reclaiming device, method, and recovery unit of CO2, H2S, or both of CO2 and H2S
11319792Processes and systems for high H2S gas processing having reduced sulfur production
6372193Process for oxidizing the H2S contained at low concentration in a gas directly to sulphur by catalytic means a
Reference

Frequently Asked Questions

Common questions about Hydrogen sulfide, answered from cross-validated data.

What is H2S?

Hydrogen sulfide is a stable, wide-gap insulating gas known for its characteristic odor and its importance as a precursor in chemical manufacturing.

More questions
What is H2S used for?
Hydrogen sulfide (H2S) is used in production of elemental sulfur, synthesis of organosulfur compounds, analytical chemistry reagent, and heavy water production.
What is the band gap of H2S?
Hydrogen sulfide (H2S) has a DFT-computed band gap of 3.52–4.43 eV across 168 reported structures.
Is H2S a metal, semiconductor, or insulator?
With a wide band gap up to 4.43 eV it is an insulator / wide-band-gap material.
Is H2S thermodynamically stable?
Yes — Hydrogen sulfide (H2S) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of H2S are known?
168 structures of H2S are reported across 5 databases, spanning 30 distinct space groups.
How is H2S synthesized?
Literature-reported routes for H2S include sol gel (2 procedures documented).
What elements does H2S contain?
Hydrogen sulfide (H2S) contains H and S (2 elements).
Where does the data for H2S come from?
H2S data is cross-referenced from latticegraph.
Comparison

How It Compares

As a foundational chalcogen hydride, hydrogen sulfide occupies a unique position in chemical databases due to its extensive structural data and established stability. Unlike more complex or unstable sulfur-based compounds, it remains a primary reference point for understanding hydrogen-sulfur bonding and molecular behavior.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze H2S in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →