CsAu

Cesium auride · Cesium gold

Cesium auride is a stable, semiconducting intermetallic compound formed from cesium and gold that exhibits unusual electronic properties.

AuCs
Crystal structure of CsAu
Ground-state structure · Materials Project
Overview

About Cesium auride

Cesium auride is a fascinating intermetallic compound that stands out for its distinct electronic behavior. Unlike many typical metallic alloys, this material acts as a semiconductor, a property that arises from the unique charge transfer between the highly electropositive cesium and the electronegative gold atoms.

Because it resides on the thermodynamic convex hull, the compound is highly stable, making it a subject of significant interest for fundamental solid-state research. Its ability to form stable structures while defying conventional metallic expectations makes it a key example of how alkali metals and noble metals can interact to create novel electronic states.

At a glance

Key Properties

Cross-validated computational properties for Cesium auride, aggregated across 3 databases.

Band Gap

1.02 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
1 DFT source

Structures

39
3 databases, 9 space groups
Uses

Applications

Where Cesium auride is used.

Fundamental solid-state physics researchStudy of ionic-metallic bonding transitions
Reference

Frequently Asked Questions

Common questions about Cesium auride, answered from cross-validated data.

What is CsAu?

Cesium auride is a stable, semiconducting intermetallic compound formed from cesium and gold that exhibits unusual electronic properties.

More questions
What is CsAu used for?
Cesium auride (CsAu) is used in fundamental solid-state physics research and study of ionic-metallic bonding transitions.
What is the band gap of CsAu?
Cesium auride (CsAu) has a DFT-computed band gap of 1.02 eV across 39 reported structures.
Is CsAu a metal, semiconductor, or insulator?
With a band gap up to 1.02 eV it is a semiconductor.
Is CsAu thermodynamically stable?
Yes — Cesium auride (CsAu) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of CsAu are known?
39 structures of CsAu are reported across 3 databases, spanning 9 distinct space groups.
What elements does CsAu contain?
Cesium auride (CsAu) contains Au and Cs (2 elements).
Where does the data for CsAu come from?
CsAu data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique intermetallic compound, CsAu serves as a primary example of an ionic-like system within the broader landscape of alkali-gold alloys. It demonstrates that combinations of these elements can result in semiconducting behavior rather than simple metallic conductivity, setting a benchmark for understanding charge transfer in binary noble metal systems.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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