Cs

Cesium · Caesium

Cesium is a highly reactive, soft alkali metal that exhibits semiconducting properties and is widely utilized in precision atomic and optical applications.

Cs
Crystal structure of Cs (tetragonal, I4/mmm (No. 139))
Ground-state structure · Materials Project
Overview

About Cesium

Cesium is a distinctive alkali metal known for its extreme reactivity and unique electronic properties. As a thermodynamically stable element, it occupies a significant position in fundamental materials science, often studied for its behavior under various structural configurations.

Its semiconducting characteristics make it a subject of interest in specialized electronic and optical research. Due to its high sensitivity to light and low ionization threshold, it serves as a critical component in high-precision instrumentation and vacuum-based technologies.

At a glance

Key Properties

Cross-validated computational properties for Cesium, aggregated across 3 databases.

Band Gap

0.14 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

50
3 databases, 14 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for Cs, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
I4/mmm (No. 139)tetragonal0.000.0000-25.1081.80
Fm-3m (No. 225)cubic0.000.0092-25.0991.79
I-43m (No. 217)cubic0.140.0126-25.0961.79
P4132 (No. 213)cubic0.000.0131-25.0951.75
I4/mmm (No. 139)tetragonal0.000.0172-25.0911.80
Im-3m (No. 229)cubic0.000.0193-25.0891.80
I4/mmm (No. 139)tetragonal0.000.0196-25.0891.78
P63/mmc (No. 194)hexagonal0.000.0198-25.0891.78
P63/mmc (No. 194)hexagonal0.000.0199-25.0891.78
Pbcm (No. 57)orthorhombic0.000.0243-25.0841.77
Pbcm (No. 57)orthorhombic0.000.0244-25.0841.77
P42/mbc (No. 135)tetragonal0.000.0275-25.0811.78
Uses

Applications

Where Cesium is used.

Atomic clocksPhotoelectric cellsVacuum tubesIon propulsion systemsSpecialty catalysts
Reference

Frequently Asked Questions

Common questions about Cesium, answered from cross-validated data.

What is Cs?

Cesium is a highly reactive, soft alkali metal that exhibits semiconducting properties and is widely utilized in precision atomic and optical applications.

More questions
What is Cs used for?
Cesium (Cs) is used in atomic clocks, photoelectric cells, vacuum tubes, ion propulsion systems, and specialty catalysts.
What is the band gap of Cs?
Cesium (Cs) has a DFT-computed band gap of 0.14 eV across 50 reported structures.
Is Cs a metal, semiconductor, or insulator?
With a band gap up to 0.14 eV it is a semiconductor.
Is Cs thermodynamically stable?
Yes — Cesium (Cs) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
What is the crystal structure of Cs?
The lowest-energy reported polymorph of Cesium (Cs) is tetragonal symmetry, space group I4/mmm (No. 139).
What is the density of Cs?
The computed density of the ground-state structure of Cesium (Cs) is 1.80 g/cm³.
How many polymorphs of Cs are known?
50 structures of Cs are reported across 3 databases, spanning 14 distinct space groups.
What elements does Cs contain?
Cesium (Cs) contains Cs (1 element).
Where does the data for Cs come from?
Cs data is cross-referenced from materials_project, mpaloe, jarvis.
Comparison

How It Compares

As a singular elemental material, Cesium stands as a foundational reference point for the study of alkali metals, providing essential data for understanding the periodic trends and structural diversity inherent in its group.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • mpaloe — Data from mpaloe.
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).

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