CaSiO3

wollastonite · calcium metasilicate

CaSiO3 is a stable, insulating calcium silicate mineral that is widely utilized in industrial manufacturing and geological research.

CaOSi
Crystal structure of CaSiO3
Ground-state structure · Materials Project
Overview

About wollastonite

CaSiO3 is a robust calcium silicate compound that exists as a thermodynamically stable phase. Its electronic character is defined by a wide band gap, classifying it as a highly effective electrical insulator that remains chemically inert under standard conditions.

This material is widely recognized for its structural versatility, appearing in numerous polymorphic forms. It serves as a fundamental component in mineralogy and materials science, where its stability and insulating nature are leveraged for high-performance industrial applications.

At a glance

Key Properties

Cross-validated computational properties for wollastonite, aggregated across 4 databases.

Band Gap

3.04–5.14 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

44
4 databases, 11 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting CaSiO3.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Solid State
Procedure available · ceder_solid_state
Uses

Applications

Where wollastonite is used.

Ceramic manufacturingConstruction materialsMetallurgical fluxFiller in plastics and paints
Intellectual Property

Patent Landscape

1 patent reference CaSiO3 or close compositional variants.

PatentTitleAssigneeGranted
12421129Copper hydroxy nitrate/calcium silicate @graphite-phase carbon nitride (Cu2(OH)3NO3/CaSiO3@g-C3N4) based photo
Reference

Frequently Asked Questions

Common questions about wollastonite, answered from cross-validated data.

What is CaSiO3?

CaSiO3 is a stable, insulating calcium silicate mineral that is widely utilized in industrial manufacturing and geological research.

More questions
What is CaSiO3 used for?
wollastonite (CaSiO3) is used in ceramic manufacturing, construction materials, metallurgical flux, and filler in plastics and paints.
What is the band gap of CaSiO3?
wollastonite (CaSiO3) has a DFT-computed band gap of 3.04–5.14 eV across 44 reported structures.
Is CaSiO3 a metal, semiconductor, or insulator?
With a wide band gap up to 5.14 eV it is an insulator / wide-band-gap material.
Is CaSiO3 thermodynamically stable?
Yes — wollastonite (CaSiO3) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
How many polymorphs of CaSiO3 are known?
44 structures of CaSiO3 are reported across 4 databases, spanning 11 distinct space groups.
How is CaSiO3 synthesized?
Literature-reported routes for CaSiO3 include sol gel, solid state (10 procedures documented).
What elements does CaSiO3 contain?
wollastonite (CaSiO3) contains Ca, O, and Si (3 elements).
Where does the data for CaSiO3 come from?
CaSiO3 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a prominent calcium silicate, CaSiO3 represents a foundational reference point for the study of silicate stability and structure, serving as a benchmark for understanding how alkaline earth metals influence the lattice dynamics of complex oxide systems.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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