CaClO2

CaClO2 is a semiconducting, thermodynamically unstable calcium oxyhalide compound characterized by a variety of potential structural forms.

CaClO
Overview

About CaClO2

CaClO2 is a calcium-based compound that exhibits semiconducting electronic properties. Its structural complexity is evidenced by multiple reported configurations across various databases, highlighting a diverse range of potential atomic arrangements for this stoichiometry. Due to its position above the thermodynamic hull, CaClO2 is considered an unstable phase under standard conditions. This metastability makes it a subject of interest for researchers investigating synthetic pathways and the limits of chemical stability in complex oxyhalide systems.

At a glance

Key Properties

Cross-validated computational properties for CaClO2, aggregated across 3 databases.

Band Gap

0.35–2.60 eV
Range across DFT structures

Energy Above Hull

0.190 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

7
3 databases, 3 space groups
Reference

Frequently Asked Questions

Common questions about CaClO2, answered from cross-validated data.

What is CaClO2?

CaClO2 is a semiconducting, thermodynamically unstable calcium oxyhalide compound characterized by a variety of potential structural forms.

More questions
What is the band gap of CaClO2?
CaClO2 has a DFT-computed band gap of 0.35–2.60 eV across 7 reported structures.
Is CaClO2 a metal, semiconductor, or insulator?
With a band gap up to 2.60 eV it is a semiconductor.
Is CaClO2 thermodynamically stable?
CaClO2 has a lowest energy above hull of 0.190 eV/atom (above hull).
How many polymorphs of CaClO2 are known?
7 structures of CaClO2 are reported across 3 databases, spanning 3 distinct space groups.
What elements does CaClO2 contain?
CaClO2 contains Ca, Cl, and O (3 elements).
Where does the data for CaClO2 come from?
CaClO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique inorganic phase with no direct structural siblings in this specific classification, CaClO2 represents an isolated point in the chemical space of calcium-chlorine-oxygen systems, serving as a case study for metastable materials synthesis.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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