CSN

CSN is a metastable, semiconducting ternary compound composed of carbon, nitrogen, and sulfur.

CNS
Overview

About CSN

CSN is a ternary compound composed of carbon, sulfur, and nitrogen. As a semiconducting material, it represents a niche area of study within inorganic chemistry, characterized by its electronic properties that bridge the gap between conductive and insulating states.

Because this compound is situated above the thermodynamic hull, it is considered a metastable phase. Its existence in multiple reported structures suggests that while it may be difficult to synthesize or maintain under standard conditions, it remains a subject of interest for fundamental materials research.

At a glance

Key Properties

Cross-validated computational properties for CSN, aggregated across 3 databases.

Band Gap

0.63 eV
Range across DFT structures

Energy Above Hull

0.445 eV/atom
Best (lowest) across sources

Stability

Above hull
1 DFT source

Structures

5
3 databases, 5 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for CSN, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
P21/c (No. 14)monoclinic0.630.4450-8.4101.80
Pm (No. 6)
Pnma (No. 62)orthorhombic0.27
P4mm (No. 99)
No. 0unknown0.27
Reference

Frequently Asked Questions

Common questions about CSN, answered from cross-validated data.

What is CSN?

CSN is a metastable, semiconducting ternary compound composed of carbon, nitrogen, and sulfur.

More questions
What is the band gap of CSN?
CSN has a DFT-computed band gap of 0.63 eV across 5 reported structures.
Is CSN a metal, semiconductor, or insulator?
With a band gap up to 0.63 eV it is a semiconductor.
Is CSN thermodynamically stable?
CSN has a lowest energy above hull of 0.445 eV/atom (above hull).
What is the crystal structure of CSN?
The lowest-energy reported polymorph of CSN is monoclinic symmetry, space group P21/c (No. 14).
What is the density of CSN?
The computed density of the ground-state structure of CSN is 1.80 g/cm³.
How many polymorphs of CSN are known?
5 structures of CSN are reported across 3 databases, spanning 5 distinct space groups.
What elements does CSN contain?
CSN contains C, N, and S (3 elements).
Where does the data for CSN come from?
CSN data is cross-referenced from materials_project, jarvis, cod.
Comparison

How It Compares

As a unique ternary system, CSN does not currently have a broad family of closely related siblings in this specific class, making its behavior distinct within the landscape of carbon-sulfur-nitrogen compounds.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).
  • cod — Data from the Crystallography Open Database. Cite: Grazulis et al., Nucleic Acids Res. 40, D420 (2012).

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