BiF4

BiF4 is a metastable semiconducting bismuth fluoride compound characterized by a high degree of structural diversity.

BiF
Crystal structure of BiF4
Ground-state structure · Materials Project
Overview

About BiF4

BiF4 is a bismuth-based fluoride compound that exhibits semiconducting electronic behavior. As a metastable phase, it represents a complex structural arrangement within the bismuth-fluorine chemical system, offering researchers a unique case study in non-equilibrium inorganic chemistry.

Its significance lies in its potential for specialized electronic applications where specific bismuth-fluorine interactions are required. Given the extensive number of reported structural variations, this compound serves as a critical point of interest for understanding phase stability and bonding in high-oxidation state bismuth fluorides.

At a glance

Key Properties

Cross-validated computational properties for BiF4, aggregated across 3 databases.

Band Gap

0.66 eV
Range across DFT structures

Energy Above Hull

0.076 eV/atom
Best (lowest) across sources

Stability

Metastable
2 DFT sources

Structures

45
3 databases, 14 space groups
Uses

Applications

Where BiF4 is used.

Fundamental materials researchElectronic property studiesSolid-state chemistry modeling
Reference

Frequently Asked Questions

Common questions about BiF4, answered from cross-validated data.

What is BiF4?

BiF4 is a metastable semiconducting bismuth fluoride compound characterized by a high degree of structural diversity.

More questions
What is BiF4 used for?
BiF4 is used in fundamental materials research, electronic property studies, and solid-state chemistry modeling.
What is the band gap of BiF4?
BiF4 has a DFT-computed band gap of 0.66 eV across 45 reported structures.
Is BiF4 a metal, semiconductor, or insulator?
With a band gap up to 0.66 eV it is a semiconductor.
Is BiF4 thermodynamically stable?
BiF4 has a lowest energy above hull of 0.076 eV/atom (metastable).
How many polymorphs of BiF4 are known?
45 structures of BiF4 are reported across 3 databases, spanning 14 distinct space groups.
What elements does BiF4 contain?
BiF4 contains Bi and F (2 elements).
Where does the data for BiF4 come from?
BiF4 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique inorganic compound, BiF4 occupies a specialized niche in materials science, serving as a distinct example of a metastable semiconductor that challenges standard structural predictions for the bismuth-fluorine binary system.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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