Bi4O5

Bi4O5 is a semiconducting bismuth oxide compound that exists in a metastable state.

BiO
Crystal structure of Bi4O5
Ground-state structure · Materials Project
Overview

About Bi4O5

Bi4O5 is a bismuth-oxygen compound characterized by its semiconducting electronic nature. As a member of the bismuth oxide family, it represents a complex stoichiometry that has been the subject of investigation across multiple structural databases.

Due to its position above the thermodynamic hull, this compound is considered metastable, making it a focus for researchers studying phase stability and synthesis pathways in bismuth-based materials.

At a glance

Key Properties

Cross-validated computational properties for Bi4O5, aggregated across 3 databases.

Band Gap

0.35–0.56 eV
Range across DFT structures

Energy Above Hull

0.150 eV/atom
Best (lowest) across sources

Stability

Above hull
2 DFT sources

Structures

9
3 databases, 1 space group
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting Bi4O5.

Solid State
Procedure available · ceder_solid_state
Reference

Frequently Asked Questions

Common questions about Bi4O5, answered from cross-validated data.

What is Bi4O5?

Bi4O5 is a semiconducting bismuth oxide compound that exists in a metastable state.

More questions
What is the band gap of Bi4O5?
Bi4O5 has a DFT-computed band gap of 0.35–0.56 eV across 9 reported structures.
Is Bi4O5 a metal, semiconductor, or insulator?
With a band gap up to 0.56 eV it is a semiconductor.
Is Bi4O5 thermodynamically stable?
Bi4O5 has a lowest energy above hull of 0.150 eV/atom (above hull).
How many polymorphs of Bi4O5 are known?
9 structures of Bi4O5 are reported across 3 databases, spanning 1 distinct space group.
How is Bi4O5 synthesized?
Literature-reported routes for Bi4O5 include solid state.
What elements does Bi4O5 contain?
Bi4O5 contains Bi and O (2 elements).
Where does the data for Bi4O5 come from?
Bi4O5 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a distinct bismuth oxide phase, Bi4O5 occupies a unique niche in the landscape of binary metal oxides. Unlike more common, highly stable oxides, it represents a specialized structural arrangement that challenges standard thermodynamic predictions, highlighting the diversity of phases possible within the bismuth-oxygen system.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

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