AgO2

AgO2 is a metallic, metastable silver oxide known for its structural complexity and diverse range of reported configurations.

AgO
Crystal structure of AgO2
Ground-state structure · Materials Project
Overview

About AgO2

AgO2 is a metallic silver-oxygen compound characterized by its complex structural landscape. With hundreds of reported configurations across various databases, it represents a highly studied system in the exploration of silver-based oxides. Its metallic nature distinguishes it from many typical insulating binary oxides, making it a subject of interest for fundamental materials research.

As a compound that resides above the thermodynamic hull, AgO2 is generally considered a metastable phase. Its existence is often tied to specific synthesis conditions that allow for the stabilization of its unique atomic arrangements, which are critical for understanding the broader chemical behavior of silver oxides under non-equilibrium conditions.

At a glance

Key Properties

Cross-validated computational properties for AgO2, aggregated across 4 databases.

Band Gap

Metallic / not reported

Energy Above Hull

0.306 eV/atom
Best (lowest) across sources

Stability

Above hull
3 DFT sources

Structures

236
4 databases, 37 space groups
Synthesis

Synthesis Routes

Literature-extracted synthesis procedures targeting AgO2.

Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Sol Gel
Procedure available · ceder_sol_gel
Uses

Applications

Where AgO2 is used.

Fundamental materials researchSolid-state chemistry studiesCatalysis exploration
Reference

Frequently Asked Questions

Common questions about AgO2, answered from cross-validated data.

What is AgO2?

AgO2 is a metallic, metastable silver oxide known for its structural complexity and diverse range of reported configurations.

More questions
What is AgO2 used for?
AgO2 is used in fundamental materials research, solid-state chemistry studies, and catalysis exploration.
What is the band gap of AgO2?
AgO2 is computed to be metallic (no band gap) in the reported DFT structures.
Is AgO2 a metal, semiconductor, or insulator?
Computed band structures report no gap, so it is metallic.
Is AgO2 thermodynamically stable?
AgO2 has a lowest energy above hull of 0.306 eV/atom (above hull).
How many polymorphs of AgO2 are known?
236 structures of AgO2 are reported across 4 databases, spanning 37 distinct space groups.
How is AgO2 synthesized?
Literature-reported routes for AgO2 include sol gel, solid state (10 procedures documented).
What elements does AgO2 contain?
AgO2 contains Ag and O (2 elements).
Where does the data for AgO2 come from?
AgO2 data is cross-referenced from latticegraph.
Comparison

How It Compares

As a unique member of the silver-oxygen system, AgO2 occupies a distinct position due to its metallic electronic character. Unlike more common, thermodynamically stable silver oxides, this compound serves as a critical case study for understanding how atomic structure influences stability and electronic properties in high-energy oxide phases.

Data sources & attribution
  • latticegraph — Lattice Graph Materials Intelligence Platform

Analyze AgO2 in the Lattice Graph platform

Polymorph comparison, confidence scoring, supply-chain risk, and patent monitoring — across 53 integrated data sources.

Explore the Platform →