Ag2SO4

Silver sulfate · Silver(I) sulfate

Silver sulfate is a stable, semiconducting inorganic salt widely used in laboratory and industrial chemical applications.

AgOS
Crystal structure of Ag2SO4 (orthorhombic, Fddd (No. 70))
Ground-state structure · Materials Project
Overview

About Silver sulfate

Silver sulfate is a thermodynamically stable inorganic compound that exists on the convex hull, indicating high structural integrity. As a semiconducting material, it serves as a key silver-containing species in various chemical processes and analytical applications.

Its structural diversity is evidenced by multiple reported configurations across scientific databases. This versatility makes it a significant subject for researchers studying silver-based salts and their roles in specialized chemical synthesis and material science.

At a glance

Key Properties

Cross-validated computational properties for Silver sulfate, aggregated across 3 databases.

Band Gap

1.23–1.32 eV
Range across DFT structures

Energy Above Hull

0.000 eV/atom
Best (lowest) across sources

Stability

On hull (stable)
2 DFT sources

Structures

6
3 databases, 3 space groups
Crystallography

Reported Structures

Lowest-energy structures reported for Ag2SO4, ranked by energy above hull.

Space GroupCrystal SystemBand Gap (eV)E above hull (eV/atom)E/atom (eV)Density (g/cm³)
Fddd (No. 70)orthorhombic1.230.0000-5.4875.43
P1 (No. 1)triclinic1.320.0306-5.4575.09
Fddd (No. 70)
P1 (No. 1)Triclinic5.09
C2 (No. 5)Monoclinic5.15
P1 (No. 1)Triclinic5.32
Uses

Applications

Where Silver sulfate is used.

Analytical chemistry reagentSilver platingWater purificationCatalysis
Reference

Frequently Asked Questions

Common questions about Silver sulfate, answered from cross-validated data.

What is Ag2SO4?

Silver sulfate is a stable, semiconducting inorganic salt widely used in laboratory and industrial chemical applications.

More questions
What is Ag2SO4 used for?
Silver sulfate (Ag2SO4) is used in analytical chemistry reagent, silver plating, water purification, and catalysis.
What is the band gap of Ag2SO4?
Silver sulfate (Ag2SO4) has a DFT-computed band gap of 1.23–1.32 eV across 6 reported structures.
Is Ag2SO4 a metal, semiconductor, or insulator?
With a band gap up to 1.32 eV it is a semiconductor.
Is Ag2SO4 thermodynamically stable?
Yes — Silver sulfate (Ag2SO4) sits on the convex hull (energy above hull 0 eV/atom), i.e. on hull (stable).
What is the crystal structure of Ag2SO4?
The lowest-energy reported polymorph of Silver sulfate (Ag2SO4) is orthorhombic symmetry, space group Fddd (No. 70).
What is the density of Ag2SO4?
The computed density of the ground-state structure of Silver sulfate (Ag2SO4) is 5.43 g/cm³.
How many polymorphs of Ag2SO4 are known?
6 structures of Ag2SO4 are reported across 3 databases, spanning 3 distinct space groups.
What elements does Ag2SO4 contain?
Silver sulfate (Ag2SO4) contains Ag, O, and S (3 elements).
Where does the data for Ag2SO4 come from?
Ag2SO4 data is cross-referenced from materials_project, jarvis, mpaloe.
Comparison

How It Compares

As a distinct silver-based sulfate, this compound occupies a unique niche in inorganic chemistry, serving as a primary reagent for silver-based applications where structural stability and predictable semiconducting behavior are required.

Data sources & attribution
  • materials_project — Data from the Materials Project. Cite: Jain et al., APL Materials 1, 011002 (2013).
  • jarvis — Data from JARVIS (NIST). Cite: Choudhary et al., npj Comp. Mater. 6, 173 (2020).
  • mpaloe — Data from mpaloe.

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